Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries

Wang, Yuesheng; Liu, Jue; Lee, Byungju; Qiao, Ruimin; Yang, Zhenzhong; Xu, Shuyin; Yu, Xiqian; Gu, Lin; Hu, Yong-Sheng; Yang, Wanli; Kang, Kisuk; Li, Hong; Yang, Xiao-Qing; Chen, Liquan; Huang, Xuejie

doi:10.1038/ncomms7401

Title: Ti-substituted tunnel-type Na_0.44MnO₂ oxide as a negative electrode for aqueous sodium-ion batteries

Journal Article · Wed Mar 25 00:00:00 EDT 2015 · Nature Communications

DOI:https://doi.org/10.1038/ncomms7401· OSTI ID:1177000

Wang, Yuesheng ^[1]; Liu, Jue ^[2]; Lee, Byungju ^[3]; Qiao, Ruimin ^[4]; Yang, Zhenzhong ^[1]; Xu, Shuyin ^[1];

^[2]; Gu, Lin ^[1];

^[1];

^[4]; Kang, Kisuk ^[3];

^[1]; Yang, Xiao-Qing ^[2]; Chen, Liquan ^[1]; Huang, Xuejie ^[1]

Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Seoul National Univ. (Korea, Republic of)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source

The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na_0.44MnO₂, were proposed, few negative electrode materials, e.g., activated carbon and NaTi₂(PO₄)₃, are available. Here we show that Ti-substituted Na_0.44MnO₂ (Na_0.44[Mn_1-xTi_x]O₂) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accurately identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na_0.44[Mn_1-xTi_x]O₂ is a promising negative electrode material for aqueous sodium-ion batteries.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC00112704

OSTI ID:: 1177000

Report Number(s):: BNL-107669-2015-JA; BNL-107669-2015-JAAM; R&D Project: MA453MAEA; VT1201000

Journal Information:: Nature Communications, Vol. 6; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 244 works

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