Catalytic process for control of NO.sub.x emissions using hydrogen
A selective catalytic reduction process with a palladium catalyst for reducing NOx in a gas, using hydrogen as a reducing agent. A zirconium sulfate (ZrO.sub.2)SO.sub.4 catalyst support material with about 0.01-2.0 wt. % Pd is applied to a catalytic bed positioned in a flow of exhaust gas at about 70-200.degree. C. The support material may be (ZrO.sub.2--SiO.sub.2)SO.sub.4. H.sub.2O and hydrogen may be injected into the exhaust gas upstream of the catalyst to a concentration of about 15-23 vol. % H.sub.2O and a molar ratio for H.sub.2/NO.sub.x in the range of 10-100. A hydrogen-containing fuel may be synthesized in an Integrated Gasification Combined Cycle power plant for combustion in a gas turbine to produce the exhaust gas flow. A portion of the fuel may be diverted for the hydrogen injection.
- Research Organization:
- Siemens Energy, Inc., Orlando, FL, (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FC26-05NT42644
- Assignee:
- Siemens Energy, Inc. (Orlando, FL)
- Patent Number(s):
- 7,718,153
- Application Number:
- 12/122,116
- OSTI ID:
- 1176302
- Resource Relation:
- Patent File Date: 2008 May 16
- Country of Publication:
- United States
- Language:
- English
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