Methods for performing electrochemical nitration reactions
Patent
·
OSTI ID:1176281
A method for the electrochemical synthesis of dinitro compounds is disclosed. The method comprises using an anode to oxidize an inactive chemical mediator, such as a ferrocyanide (Fe(CN).sub.6.sup.-4) ion, to an active chemical mediator or oxidizing agent, such as a ferricyanide (Fe(CN).sub.6.sup.-3) ion, in the presence of a differential voltage. The oxidizing agent reacts with a nitro compound and a nitrite ion to form a geminal dinitro compound. The anode may continuously oxidize ferrocyanide to regenerate active ferricyanide, thus keeping sufficient amounts of ferricyanide available for reaction..
- Research Organization:
- Idaho National Laboratory (INL), Idaho Falls, ID (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC07-05ID14517
- Assignee:
- Battelle Energy Alliance, LLC (Idaho Falls, ID)
- Patent Number(s):
- 7,713,401
- Application Number:
- 11/836,009
- OSTI ID:
- 1176281
- Country of Publication:
- United States
- Language:
- English
Catalyzed Oxidative Nitration of Nitronate Salts
|
journal | May 1985 |
Electrolytic preparation of gem-dinitroparaffins
|
journal | June 1963 |
Electrochemical synthesis of geminal azidonitro compounds
|
journal | November 2004 |
Substitution reactions which proceed via radical anion intermediates. 26. Oxidative substitution of nitroparaffin salts
|
journal | February 1983 |
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