Directed assembly of three-dimensional structures with micron-scale features

Gratson, Gregory; Lewis, Jennifer A.

Title: Directed assembly of three-dimensional structures with micron-scale features

Patent · Tue Nov 28 00:00:00 EST 2006

OSTI ID:1176007

Gratson, Gregory; Lewis, Jennifer A.

The invention provides polyelectrolyte inks comprising a solvent, a cationic polyelectrolyte, dissolved in the solvent, and an anionic polyelectrolyte, dissolved in the solvent. The concentration of at least one of the polyelectrolytes in the solvent is in a semidilute regime.

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Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-91ER45439

Assignee:: The Board of Trustees of the University of Illinois (Urbana, IL)

Patent Number(s):: 7,141,617

Application Number:: 10/463,834

OSTI ID:: 1176007

Resource Relation:: Patent File Date: 2003 Jun 17

Country of Publication:: United States

Language:: English

References (82)

Artificial Spinning of Spider Silk Seidel, Andreas; Liivak, Oskar; Jelinski, Lynn W. Macromolecules, Vol. 31, Issue 19 https://doi.org/10.1021/ma9808880	journal	September 1998
Fabrication of Complex Three-Dimensional Microchannel Systems in PDMS Wu, Hongkai; Odom, Teri W.; Chiu, Daniel T. Journal of the American Chemical Society, Vol. 125, Issue 2 https://doi.org/10.1021/ja021045y	journal	January 2003
The effect of anionic polyelectrolytes on the properties of aqueous silicon nitride suspensions Laarz, Eric; Bergström, Lennart Journal of the European Ceramic Society, Vol. 20, Issue 4 https://doi.org/10.1016/S0955-2219(99)00187-9	journal	April 2000
Microfabricated Multiphase Packed-Bed Reactors: Characterization of Mass Transfer and Reactions Losey, Matthew W.; Schmidt, Martin A.; Jensen, Klavs F. Industrial & Engineering Chemistry Research, Vol. 40, Issue 12 https://doi.org/10.1021/ie000523f	journal	June 2001
Macroions in Salty Water with Multivalent Ions: Giant Inversion of Charge Nguyen, T. T.; Grosberg, A. Yu.; Shklovskii, B. I. Physical Review Letters, Vol. 85, Issue 7 https://doi.org/10.1103/PhysRevLett.85.1568	journal	August 2000
Phase separation of binary liquid mixtures of hard spheres and Yukawa particles Garibay-Alonso, R.; Méndez-Alcaraz, J. M.; Klein, R. Physica A: Statistical Mechanics and its Applications, Vol. 235, Issue 1-2 https://doi.org/10.1016/S0378-4371(96)00337-8	journal	January 1997
Microporous materials: Electrochemically grown photonic crystals Braun, Paul V.; Wiltzius, Pierre Nature, Vol. 402, Issue 6762, p. 603-604 https://doi.org/10.1038/45137	journal	December 1999
Conjugated Polymer Inverse Opals for Potentiometric Biosensing Cassagneau, T.; Caruso, F. Advanced Materials, Vol. 14, Issue 24 https://doi.org/10.1002/adma.200290014	journal	December 2002
Microfluidics for complex computation? Moor, S. K. IEEE Spectrum, Vol. 38, Issue 6 https://doi.org/10.1109/MSPEC.2001.925279	journal	June 2001
Processing of Highly Concentrated Aqueous alpha-Alumina Suspensions Stabilized with Polyelectrolytes Cesarano, Joseph; Aksay, Ilhan A. Journal of the American Ceramic Society, Vol. 71, Issue 12 https://doi.org/10.1111/j.1151-2916.1988.tb05792.x	journal	December 1988
Structure of binary colloidal mixtures of charged and uncharged spherical particles Mendez-Alcaraz, J. M.; D'Aguanno, B.; Klein, R. Langmuir, Vol. 8, Issue 12 https://doi.org/10.1021/la00048a012	journal	December 1992
MATERIALS PROCESSING: The Power of Direct Writing Chrisey, D. B. Science, Vol. 289, Issue 5481 https://doi.org/10.1126/science.289.5481.879	journal	August 2000
Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication Cumpston, Brian H.; Ananthavel, Sundaravel P.; Barlow, Stephen Nature, Vol. 398, Issue 6722, p. 51-54 https://doi.org/10.1038/17989	journal	March 1999
Transient gelation by spinodal decomposition in colloid-polymer mixtures Verhaegh, Nynke A. M.; Asnaghi, Daniela; Lekkerkerker, Henk N. W. Physica A: Statistical Mechanics and its Applications, Vol. 242, Issue 1-2 https://doi.org/10.1016/S0378-4371(97)00184-2	journal	August 1997
Colloidal Inks for Directed Assembly of 3-D Periodic Structures Smay, James E.; Cesarano, Joseph; Lewis, Jennifer A. Langmuir, Vol. 18, Issue 14, p. 5429-5437 https://doi.org/10.1021/la0257135	journal	July 2002
Polymers with Complex Architecture by Living Anionic Polymerization Hadjichristidis, Nikos; Pitsikalis, Marinos; Pispas, Stergios Chemical Reviews, Vol. 101, Issue 12 https://doi.org/10.1021/cr9901337	journal	December 2001
Adsorption of small, positive particles onto large, negative particles in the presence of polymer. Part 1.—Adsorption isotherms Vincent, Brian; Young, Colin A.; Tadros, Tharwat F. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 76, Issue 0 https://doi.org/10.1039/f19807600665	journal	January 1980
On-chip natural assembly of silicon photonic bandgap crystals Vlasov, Yurii A.; Bo, Xiang-Zheng; Sturm, James C. Nature, Vol. 414, Issue 6861, p. 289-293 https://doi.org/10.1038/35104529	journal	November 2001
Influence of Various Types of Inorganic Salts on Dispersion Mechanisms of Comb-Type Polymer Containing Grafted Polyethylene Oxides Chains. [櫛形高分子の分散作用に及ぼす無機電解質の影響] Sakai, Etsuo; Kawakami, Akira; Hamamoto, Hiroaki Journal of the Ceramic Society of Japan, Vol. 108, Issue 1262 https://doi.org/10.2109/jcersj.108.1262_904	journal	January 2000
An Integrated Nanoliter DNA Analysis Device Burns, M. A. Science, Vol. 282, Issue 5388 https://doi.org/10.1126/science.282.5388.484	journal	October 1998
The development of chaotic advection Aref, Hassan Physics of Fluids, Vol. 14, Issue 4 https://doi.org/10.1063/1.1458932	journal	April 2002
Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites Decher, G. Science, Vol. 277, Issue 5330 https://doi.org/10.1126/science.277.5330.1232	journal	August 1997
Branched biodegradable polyesters for parenteral drug delivery systems Breitenbach, Armin; Li, You Xin; Kissel, Thomas Journal of Controlled Release, Vol. 64, Issue 1-3 https://doi.org/10.1016/S0168-3659(99)00134-0	journal	February 2000
Electrochemical Fabrication of 3D Microperiodic Porous Materials Braun, P. V.; Wiltzius, P. Advanced Materials, Vol. 13, Issue 7, p. 482-485 https://doi.org/10.1002/1521-4095(200104)13:7<482::AID-ADMA482>3.0.CO;2-4	journal	April 2001
The controlled flocculation of particulate dispersions using small particles of opposite charge. III. Investigation of floc structure using rheological techniques Luckham, P. F.; Vincent, B.; Tadros, Th. F. Colloids and Surfaces, Vol. 6, Issue 2 https://doi.org/10.1016/0166-6622(83)80089-4	journal	March 1983
Exploring the Rules for Selective Deposition: Interactions of Model Polyamines on Acid and Oligoethylene Oxide Surfaces Jiang, Xueping; Ortiz, Christine; Hammond, Paula T. Langmuir, Vol. 18, Issue 4 https://doi.org/10.1021/la010832q	journal	February 2002
Spider Silk Fibers Spun from Soluble Recombinant Silk Produced in Mammalian Cells Lazaris, A. Science, Vol. 295, Issue 5554 https://doi.org/10.1126/science.1065780	journal	January 2002
Pervaporation separation of water/alcohol mixtures using composite membranes based on polyelectrolyte multilayer assemblies Meier-Haack, Jochen; Lenk, Wolfgang; Lehmann, Dieter Journal of Membrane Science, Vol. 184, Issue 2 https://doi.org/10.1016/S0376-7388(00)00618-9	journal	March 2001
Interactions between Mica Surfaces in Sodium Polyacrylate Solutions Containing Calcium Ions Berg, Johan M.; Claesson, Per M.; Neuman, Ronald D. Journal of Colloid and Interface Science, Vol. 161, Issue 1 https://doi.org/10.1006/jcis.1993.1457	journal	November 1993
Depletion forces in colloidal mixtures Méndez-Alcaraz, J. M.; Klein, R. Physical Review E, Vol. 61, Issue 4 https://doi.org/10.1103/PhysRevE.61.4095	journal	April 2000
Synthesis of Combs, Centipedes, and Barbwires: Poly(isoprene- graft -styrene) Regular Multigraft Copolymers with Trifunctional, Tetrafunctional, and Hexafunctional Branch Points Uhrig, David; Mays, Jimmy W. Macromolecules, Vol. 35, Issue 19 https://doi.org/10.1021/ma020427l	journal	September 2002
Macroion Attraction Due to Electrostatic Correlation between Screening Counterions. 1. Mobile Surface-Adsorbed Ions and Diffuse Ion Cloud Rouzina, Ioulia; Bloomfield, Victor A. The Journal of Physical Chemistry, Vol. 100, Issue 23 https://doi.org/10.1021/jp960458g	journal	January 1996
Dispersion mechanisms of comb-type superplasticizers containing grafted poly(ethylene oxide) chains Sakai, Etsuo; Kawakami, Akira; Daimon, Masaki Macromolecular Symposia, Vol. 175, Issue 1, p. 367-376 https://doi.org/10.1002/1521-3900(200110)175:1<367::AID-MASY367>3.0.CO;2-9	journal	October 2001
Stability of Aqueous alpha-Al2O3 Suspensions with Poly(methacrylic acid) Polyelectrolyte Cesarano, Joseph; Aksay, Ilhan A.; Bleier, Alan Journal of the American Ceramic Society, Vol. 71, Issue 4 https://doi.org/10.1111/j.1151-2916.1988.tb05855.x	journal	April 1988
Nanoparticle Inks for Directed Assembly of Three-Dimensional Periodic Structures Li, Q.; Lewis, J. A. Advanced Materials, Vol. 15, Issue 19 https://doi.org/10.1002/adma.200305413	journal	October 2003
Full Three-Dimensional Photonic Bandgap Crystals at Near-Infrared Wavelengths Noda, S. Science, Vol. 289, Issue 5479 https://doi.org/10.1126/science.289.5479.604	journal	July 2000
Interaction between Dissolved Ba ²⁺ and PAA-NH ₄ Dispersant in Aqueous Barium Titanate Suspensions Li, Chia-Chen; Jean, Jau-Ho Journal of the American Ceramic Society, Vol. 85, Issue 6 https://doi.org/10.1111/j.1151-2916.2002.tb00295.x	journal	June 2002
Effect of a comb-like amphiphilic polymer on the stability of alumina dispersions Li, Chin; Yu, Xiang; Somasundaran, P. Colloids and Surfaces, Vol. 69, Issue 2-3 https://doi.org/10.1016/0166-6622(92)80226-R	journal	December 1992
Photonic-bandgap microcavities in optical waveguides Foresi, J. S.; Villeneuve, P. R.; Ferrera, J. Nature, Vol. 390, Issue 6656, p. 143-145 https://doi.org/10.1038/36514	journal	November 1997
Active microfluidic mixer for mixing of microparticles and liquids Choi, Jin-Woo; Ahn, Chong H. Micromachining and Microfabrication, SPIE Proceedings https://doi.org/10.1117/12.395652	conference	August 2000
Autonomic healing of polymer composites White, S. R.; Sottos, N. R.; Geubelle, P. H. Nature, Vol. 409, Issue 6822, p. 794-797 https://doi.org/10.1038/35057232	journal	February 2001
Effect of Counterion Valency and Ionic Strength on Polyelectrolyte Adsorption Dahlgren, Mats A. G. Langmuir, Vol. 10, Issue 5 https://doi.org/10.1021/la00017a042	journal	May 1994
3-D STRUCTURES FROM STABLE GELS: Automated method builds precision parts from tailor-made colloidal inks Jacoby, Mitch Chemical & Engineering News Archive, Vol. 80, Issue 26 https://doi.org/10.1021/cen-v080n026.p007	journal	July 2002
An Integrated Fluorescence Detection System in Poly(dimethylsiloxane) for Microfluidic Applications Chabinyc, Michael L.; Chiu, Daniel T.; McDonald, J. Cooper Analytical Chemistry, Vol. 73, Issue 18 https://doi.org/10.1021/ac010423z	journal	September 2001
Aggregation in concentrated kaolin suspensions stabilized by polyacrylate Stenius, Per; Järnström, Lars; Rigdahl, Mikael Colloids and Surfaces, Vol. 51 https://doi.org/10.1016/0166-6622(90)80143-R	journal	January 1990
Layered, Erasable, Ultrathin Polymer Films Sukhishvili, Svetlana A.; Granick, Steve Journal of the American Chemical Society, Vol. 122, Issue 39 https://doi.org/10.1021/ja002410t	journal	October 2000
Microfluidic Device for Combinatorial Fusion of Liposomes and Cells Strömberg, Anette; Karlsson, Anders; Ryttsén, Frida Analytical Chemistry, Vol. 73, Issue 1 https://doi.org/10.1021/ac000528m	journal	January 2001
Nanoparticle halos: A new colloid stabilization mechanism Tohver, V.; Smay, J. E.; Braem, A. Proceedings of the National Academy of Sciences, Vol. 98, Issue 16 https://doi.org/10.1073/pnas.151063098	journal	July 2001
Cascade of Coil-Globule Conformational Transitions of Single Flexible Polyelectrolyte Molecules in Poor Solvent Kiriy, Anton; Gorodyska, Ganna; Minko, Sergiy Journal of the American Chemical Society, Vol. 124, Issue 45 https://doi.org/10.1021/ja0261168	journal	November 2002
Fabrication of photonic crystals by deep x-ray lithography Feiertag, G.; Ehrfeld, W.; Freimuth, H. Applied Physics Letters, Vol. 71, Issue 11 https://doi.org/10.1063/1.120431	journal	September 1997
Direct-write assembly of ceramics from colloidal inks Lewis, Jennifer A. Current Opinion in Solid State and Materials Science, Vol. 6, Issue 3 https://doi.org/10.1016/S1359-0286(02)00031-1	journal	June 2002
Nanoparticle Engineering of Complex Fluid Behavior Tohver, Valeria; Chan, Angel; Sakurada, Osamu Langmuir, Vol. 17, Issue 26 https://doi.org/10.1021/la011252w	journal	December 2001
Formation and collapse of gels of sterically stabilized colloidal particles Weeks, James R.; Duijneveldt, Jeroen S. van; Vincent, Brian Journal of Physics: Condensed Matter, Vol. 12, Issue 46 https://doi.org/10.1088/0953-8984/12/46/307	journal	October 2000
Fabrication of photonic crystals for the visible spectrum by holographic lithography Campbell, M.; Sharp, D. N.; Harrison, M. T. Nature, Vol. 404, Issue 6773, p. 53-56 https://doi.org/10.1038/35003523	journal	March 2000
Adsorption of polyelectrolytes onto oxides — the influence of ionic strength, molar mass, and Ca2+ ions Vermöhlen, K.; Lewandowski, H.; Narres, H. -D Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 163, Issue 1 https://doi.org/10.1016/S0927-7757(99)00429-X	journal	March 2000
Rheological behavior of highly concentrated aqueous calcium carbonate suspensions in the presence of polyelectrolytes Tobori, Norio; Amari, Takeshi Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 215, Issue 1-3 https://doi.org/10.1016/S0927-7757(02)00421-1	journal	March 2003
Understanding thixotropic and antithixotropic behavior of viscoelastic micellar solutions and liquid crystalline dispersions. I. The model Bautista, F.; de Santos, J. M.; Puig, J. E. Journal of Non-Newtonian Fluid Mechanics, Vol. 80, Issue 2-3 https://doi.org/10.1016/S0377-0257(98)00081-0	journal	January 1999
Optical spectroscopy of high dielectric contrast 3D photonic crystals Braun, P. V.; Zehner, R. W.; White, C. A. Europhysics Letters (EPL), Vol. 56, Issue 2 https://doi.org/10.1209/epl/i2001-00507-2	journal	October 2001
Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal Templating Caruso, F. Science, Vol. 282, Issue 5391 https://doi.org/10.1126/science.282.5391.1111	journal	November 1998
Generation of Solution and Surface Gradients Using Microfluidic Systems Jeon, Noo Li; Dertinger, Stephan K. W.; Chiu, Daniel T. Langmuir, Vol. 16, Issue 22 https://doi.org/10.1021/la000600b	journal	October 2000
Rapid prototyping of scaffolds derived from thermoreversible hydrogels and tailored for applications in tissue engineering Landers, Rüdiger; Hübner, Ute; Schmelzeisen, Rainer Biomaterials, Vol. 23, Issue 23 https://doi.org/10.1016/S0142-9612(02)00139-4	journal	December 2002
Transient gels in colloid–polymer mixtures studied with fluorescence confocal scanning laser microscopy Verhaegh, Nynke A. M.; Asnaghi, Daniela; Lekkerkerker, Henk N. W. Physica A: Statistical Mechanics and its Applications, Vol. 264, Issue 1-2 https://doi.org/10.1016/S0378-4371(98)00420-8	journal	February 1999
Direct Patterning of Modified Oligonucleotides on Metals and Insulators by Dip-Pen Nanolithography Demers, L. M. Science, Vol. 296, Issue 5574 https://doi.org/10.1126/science.1071480	journal	June 2002
Rapid prototyping of patterned functional nanostructures Fan, Hongyou; Lu, Yunfeng; Stump, Aaron Nature, Vol. 405, Issue 6782 https://doi.org/10.1038/35011026	journal	May 2000
Fabrication of Topologically Complex Three-Dimensional Microfluidic Systems in PDMS by Rapid Prototyping Anderson, Janelle R.; Chiu, Daniel T.; Jackman, Rebecca J. Analytical Chemistry, Vol. 72, Issue 14 https://doi.org/10.1021/ac9912294	journal	July 2000
Rheology of colloidal suspensions: Case of lubricating greases Mas, Rémy; Magnin, Albert Journal of Rheology, Vol. 38, Issue 4 https://doi.org/10.1122/1.550598	journal	July 1994
Structural properties of colloidal suspensions Méndez-Alcaraz, J. M.; Chávez-Páez, M.; D'Aguanno, B. Physica A: Statistical Mechanics and its Applications, Vol. 220, Issue 1-2 https://doi.org/10.1016/0378-4371(95)00112-K	journal	October 1995
A New Class of Complex Water-soluble Polyelectrolytes Zezin, Aleksandr B.; Kabanov, Viktor A. Russian Chemical Reviews, Vol. 51, Issue 9 https://doi.org/10.1070/RC1982v051n09ABEH002921	journal	September 1982
Cation-Induced Collapse of Low-Molecular-Weight Polyacrylic Acid in the Dispersion of Barium Titanate Bell, Nelson S.; Sindel, Jürgen; Aldinger, F. Journal of Colloid and Interface Science, Vol. 254, Issue 2 https://doi.org/10.1006/jcis.2002.8557	journal	October 2002
Mixtures of charged colloids and nonadsorbing flexible polyelectrolytes: An integral equation study Ferreira, Paula G.; Dymitrowska, Magdalena; Belloni, Luc The Journal of Chemical Physics, Vol. 113, Issue 21 https://doi.org/10.1063/1.1322083	journal	December 2000
Polymer-on-Polymer Stamping: Universal Approaches to Chemically Patterned Surfaces Jiang, Xueping; Zheng, Haipeng; Gourdin, Shoshana Langmuir, Vol. 18, Issue 7, p. 2607-2615 https://doi.org/10.1021/la011098d	journal	April 2002
Geometric Control of Cell Life and Death Chen, C. S. Science, Vol. 276, Issue 5317 https://doi.org/10.1126/science.276.5317.1425	journal	May 1997
Nanoporous Thin Films Formed by Salt-Induced Structural Changes in Multilayers of Poly(acrylic acid) and Poly(allylamine) Fery, Andreas; Schöler, Björn; Cassagneau, Thierry Langmuir, Vol. 17, Issue 13 https://doi.org/10.1021/la0102612	journal	June 2001
A three-dimensional photonic crystal operating at infrared wavelengths Lin, S. Y.; Fleming, J. G.; Hetherington, D. L. Nature, Vol. 394, Issue 6690, p. 251-253 https://doi.org/10.1038/28343	journal	July 1998
Liquid crystalline spinning of spider silk Vollrath, Fritz; Knight, David P. Nature, Vol. 410, Issue 6828 https://doi.org/10.1038/35069000	journal	March 2001
Experimental investigations of the interaction forces in concentrated dispersions de L. Costello, B. A.; Kim, I. T.; Luckham, P. F. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 77, Issue 1 https://doi.org/10.1016/0927-7757(93)80099-Z	journal	September 1993
"Dip-Pen" Nanolithography Piner, Richard D.; Zhu, Jin; Xu, Feng Science, Vol. 283, Issue 5402 https://doi.org/10.1126/science.283.5402.661	journal	January 1999
Effective forces between macroions: The cases of asymmetric macroions and added salt Allahyarov, E.; Löwen, H.; Trigger, S. Physical Review E, Vol. 57, Issue 5 https://doi.org/10.1103/PhysRevE.57.5818	journal	May 1998
Characterizing nanoparticle interactions: Linking models to experiments Ramakrishnan, S.; Zukoski, C. F. The Journal of Chemical Physics, Vol. 113, Issue 3 https://doi.org/10.1063/1.481901	journal	July 2000
A microfabricated device for sizing and sorting DNA molecules Chou, H. -P.; Spence, C.; Scherer, A. Proceedings of the National Academy of Sciences, Vol. 96, Issue 1 https://doi.org/10.1073/pnas.96.1.11	journal	January 1999
Attraction between Like-Charged Macroions by Coulomb Depletion Allahyarov, E.; D'Amico, I.; Löwen, H. Physical Review Letters, Vol. 81, Issue 6 https://doi.org/10.1103/PhysRevLett.81.1334	journal	August 1998
Adsorption/desorption of a PEO-rich comb-like polymer at a silica/aqueous solution interface Orgeret-Ravanat, C.; Gramain, Ph.; Dejardin, Ph. Colloids and Surfaces, Vol. 33 https://doi.org/10.1016/0166-6622(88)80053-2	journal	January 1988

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