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Title: Photoelectrochemical molecular comb

Patent ·
OSTI ID:1175870

A method and apparatus for separating molecules. The apparatus includes a substrate having a surface. A film in contact with the surface defines a substrate/film interface. An electrode electrically connected to the film applies a voltage potential between the electrode and the substrate to form a depletion region in the substrate at the substrate/film interface. A photon energy source having an energy level greater than the potential is directed at the depletion region to form electron-hole pairs in the depletion region. At least one of the electron-hole pairs is separated by the potential into an independent electron and an independent hole having opposite charges and move in opposing directions. One of the electron and hole reach the substrate/film interface to create a photopotential in the film causing charged molecules in the film to move in response to the localized photovoltage.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-00OR22725
Assignee:
UT-Battelle LLC (Oak Ridge, TN)
Patent Number(s):
7,090,757
Application Number:
10/077,633
OSTI ID:
1175870
Country of Publication:
United States
Language:
English

References (5)

Chemical-imaging sensor using enzyme journal April 1996
Heterogeneous integration through electrokinetic migration journal January 2001
Photoelectrophoretic Transport and Hybridization of DNA Oligonucleotides on Unpatterned Silicon Substrates journal September 2000
Development and characterization of a titanium dioxide-based semiconductor photoelectrochemical detector journal February 1992
The Light-Addressable Potentiometric Sensor: Principles and Biological Applications journal June 1994

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