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Title: Magnetic process for removing heavy metals from water employing magnetites

Patent ·
OSTI ID:1174406

A process for removing heavy metals from water is provided. The process includes the steps of introducing magnetite to a quantity of water containing heavy metal. The magnetite is mixed with the water such that at least a portion of, and preferably the majority of, the heavy metal in the water is bound to the magnetite. Once this occurs the magnetite and absorbed metal is removed from the water by application of a magnetic field. In most applications the process is achieved by flowing the water through a solid magnetized matrix, such as steel wool, such that the magnetite magnetically binds to the solid matrix. The magnetized matrix preferably has remnant magnetism, but may also be subject to an externally applied magnetic field. Once the magnetite and associated heavy metal is bound to the matrix, it can be removed and disposed of, such as by reverse water or air and water flow through the matrix. The magnetite may be formed in-situ by the addition of the necessary quantities of Fe(II) and Fe(III) ions, or pre-formed magnetite may be added, or a combination of seed and in-situ formation may be used. The invention also relates to an apparatus for performing the removal of heavy metals from water using the process outlined above.

Research Organization:
Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
W-7405-ENG-36
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Number(s):
6,596,182
Application Number:
09/776,608
OSTI ID:
1174406
Country of Publication:
United States
Language:
English

References (5)

Magnetic filtration journal September 1973
Ambient-temperature synthesis of metal-bearing ferrites: how and why? journal August 1999
Precipitation and densification of magnetic iron compounds from aqueous solutions at room temperature journal November 1998
Fundamental Study of an Ambient Temperature Ferrite Process in the Treatment of Acid Mine Drainage journal January 1996
The Sirofloc Process at Redmires Water‐Treatment Works journal February 1992

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