The photoelectron spectrum of ArXe obtained using resonantly enhanced multiphoton ionization

Journal Article · Tue Jan 01 04:00:00 EST 1985 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.448566· OSTI ID:1169911

Pratt, Stephen T. ^[1]; Dehmer, Patricia M. ^[1]; Dehmer, Joseph L. ^[1]

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1. Argonne National Laboratory (ANL), Argonne, IL (United States)

The photoelectron spectrum of the heteronuclear rare gas dimer ArXe was determined using resonantly enhanced multiphoton ionization-photoelectron spectroscopy (REMPI-PES). Three photoelectron peaks are observed corresponding to the production of ArXe⁺ in the A²Σ⁺ _1/2B ²Π_3/2, and B ²Π_1/2 states. The kinetic energies of these peaks are used to determine lower limits for the dissociation energies of the ionic states.

• Research Organization: Argonne National Laboratory (ANL), Argonne, IL (United States)
• Sponsoring Organization: USDOE; Office of Naval Research
• DOE Contract Number: W-31109-ENG-38
• OSTI ID: 1169911
• Journal Information: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 12 Vol. 82; ISSN JCPSA6; ISSN 0021-9606
• Publisher: American Institute of Physics (AIP)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS