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Title: Actinide-ion sensor

Patent ·
OSTI ID:1167223

An apparatus for the real-time, in-situ monitoring of actinide-ion concentrations. A working electrolyte is positioned within the interior of a container. The working electrolyte is separated from a reference electrolyte by a separator. A working electrode is at least partially in contact with the working electrolyte. A reference electrode is at least partially in contact with the reference electrolyte. A voltmeter is electrically connected to the working electrode and the reference electrode. The working electrolyte comprises an actinide-ion of interest. The separator is ionically conductive to the actinide-ion of interest. The separator comprises an actinide, Zr, and Nb. Preferably, the actinide of the separator is Am or Np, more preferably Pu. In one embodiment, the actinide of the separator is the actinide of interest. In another embodiment, the separator further comprises P and O.

Research Organization:
Idaho National Laboratory (INL), Idaho Falls, ID (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC07-05ID14517
Assignee:
U.S. Department of Energy (Washington, DC)
Patent Number(s):
8,932,446
Application Number:
13/891,308
OSTI ID:
1167223
Resource Relation:
Patent File Date: 2013 May 10
Country of Publication:
United States
Language:
English

References (3)

Uranyl ion selective electrode patent January 1989
Application of calixarene ionophores in PVC based ISEs for uranium detection journal March 2001
Highly selective and sensitive Th4+-PVC-based membrane sensor based on 2-(diphenylphosphorothioyl)-N′,N′-diphenylacetamide journal March 2007

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