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Highly-Ordered Titania Nanotube Arrays: Architecture-Property Relationships for Efficient, Wideband Solar-Generation of Hydrogen

Technical Report ·
DOI:https://doi.org/10.2172/1164519· OSTI ID:1164519
 [1]
  1. Pennsylvania State Univ., University Park, PA (United States); The Pennsylvania State University
Under program auspices we have investigated material chemistries suitable for the solar generation of hydrogen by water photoelectrolysis. We have built upon, and extended, our knowledge base on the synthesis and application of TiO2 nanotube arrays, a material architecture that appears ideal for water photoelectrolysis. To date we have optimized, refined, and greatly extended synthesis techniques suitable for achieving highly ordered TiO2 nanotube arrays of given length, wall thickness, pore diameter, and tube-to-tube spacing for use in water photoelectrolysis. We have built upon this knowledge based to achieve visible light responsive, photocorrosion stable n-type and p-type ternary oxide nanotube arrays for use in photoelectrochemical diodes.
Research Organization:
Pennsylvania State Univ., University Park, PA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
FG02-06ER15772
OSTI ID:
1164519
Country of Publication:
United States
Language:
English

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