Fluorination of “brick and mortar” soft-templated graphitic ordered mesoporous carbons for high power lithium-ion battery

Journal Article · Mon Mar 18 04:00:00 EDT 2013 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c3ta10710h· OSTI ID:1154781

Fulvio, Pasquale F. ^[1]; Veith, Gabriel M. ^[2]; Adcock, Jamie L. ^[3]; Brown, Suree S. ^[3]; Mayes, Richard T. ^[1]; Wang, Xiqing ^[1]; Mahurin, Shannon M. ^[1]; Guo, Bingkun ^[1]; Sun, Xiao-Guang ^[1]; Puretzky, Alex A. ^[4]; Rouleau, Christopher M. ^[4]; Geohegan, David B. ^[4]; Dai, Sheng ^[5]

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1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences
2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
3. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science
5. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

We prepared ordered mesoporous carbon graphitic carbon composites by the brick and mortar fluorinated methodusing F₂ and investigated as cathodes for primary lithium batteries. Our resulting materials have a rich array of C F species, asmeasured by XPS, which influence conduction and voltage profiles.

• Research Organization: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
• Sponsoring Organization: USDOE Office of Science (SC)
• DOE Contract Number: AC05-00OR22725
• OSTI ID: 1154781
• Journal Information: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 33 Vol. 1; ISSN 2050-7488; ISSN JMCAET
• Publisher: Royal Society of Chemistry
• Country of Publication: United States
• Language: English

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE