The state and catalytic properties of (Ni + Pd)/SiO{sub 2} systems obtained by grafting organometallic complexes on the surface of SiO{sub 2}
Journal Article
·
· Kinetics and Catalysis
OSTI ID:114990
- Institute of Chemistry of Natural Raw Organic Materials, Krasnoyarsk (Russian Federation); and others
The adsorption and catalytic properties of Pd/SiO{sub 2}, Ni/SiO{sub 2}, and (Pd + Ni)/SiO{sub 2} samples obtained by grafting organometallic Pd and Ni compounds on the support surface are studied. Bimetallic Pd-Ni catalysts are shown to have an additive catalytic action in the hydrogenation of benzene. Synergistic effects are detected in the reactions of ethane hydrogenolysis, CO hydrogenation, and propylene hydroformylation. The obtained data show that the surface of bimetallic cluster particles becomes enriched with palladium atoms.
- OSTI ID:
- 114990
- Journal Information:
- Kinetics and Catalysis, Journal Name: Kinetics and Catalysis Journal Issue: 3 Vol. 36; ISSN 0023-1584; ISSN KICAA8
- Country of Publication:
- United States
- Language:
- English
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