The importance of experimental design on measurement of dynamic interfacial tension and interfacial rheology in diffusion-limited surfactant systems

Reichert, Matthew D.; Alvarez, Nicolas J.; Brooks, Carlton F.; Grillet, Anne M.; Mondy, Lisa A.; Anna, Shelley L.; Walker, Lynn M.

doi:10.1016/j.colsurfa.2014.11.035

Title: The importance of experimental design on measurement of dynamic interfacial tension and interfacial rheology in diffusion-limited surfactant systems

Journal Article · Wed Sep 24 00:00:00 EDT 2014 · Colloids and Surfaces. A, Physicochemical and Engineering Aspects

DOI:https://doi.org/10.1016/j.colsurfa.2014.11.035· OSTI ID:1140848

Reichert, Matthew D. ^[1]; Alvarez, Nicolas J. ^[1]; Brooks, Carlton F. ^[2]; Grillet, Anne M. ^[2]; Mondy, Lisa A. ^[2]; Anna, Shelley L. ^[1]; Walker, Lynn M. ^[1]

Carnegie Mellon Univ., Pittsburgh, PA (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Pendant bubble and drop devices are invaluable tools in understanding surfactant behavior at fluid–fluid interfaces. The simple instrumentation and analysis are used widely to determine adsorption isotherms, transport parameters, and interfacial rheology. However, much of the analysis performed is developed for planar interfaces. Moreover, the application of a planar analysis to drops and bubbles (curved interfaces) can lead to erroneous and unphysical results. We revisit this analysis for a well-studied surfactant system at air–water interfaces over a wide range of curvatures as applied to both expansion/contraction experiments and interfacial elasticity measurements. The impact of curvature and transport on measured properties is quantified and compared to other scaling relationships in the literature. Our results provide tools to design interfacial experiments for accurate determination of isotherm, transport and elastic properties.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1140848

Alternate ID(s):: OSTI ID: 1433259

Report Number(s):: SAND-2014-1837J; PII: S0927775714008905

Journal Information:: Colloids and Surfaces. A, Physicochemical and Engineering Aspects, Vol. 467, Issue C; ISSN 0927-7757

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 40 works

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Title: The importance of experimental design on measurement of dynamic interfacial tension and interfacial rheology in diffusion-limited surfactant systems

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