Synthesis and Lanthanide Coordination Chemistry of Phosphine Oxide Decorated Dibenzothiophene and Dibenzothiophene Sulfone Platforms

Journal Article · Tue Dec 31 23:00:00 EST 2013 · Inorganic Chemistry

DOI:https://doi.org/10.1021/ic500471w· OSTI ID:1134649

Rosario-Amorin, Daniel ^[1]; Ouizem, Sabrina ^[1]; Dickie, D. A. ^[1]; Paine, Robert T. ^[1]; Cramer, Roger E. ^[2]; Hay, Benjamin ^[3]; Podair, Julien ^[3]; Delmau, Laetitia Helene ^[3]

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1. University of New Mexico, Albuquerque
2. University of Hawaii
3. ORNL

Syntheses for new ligands based upon dibenzothiophene and dibenzothiophene sulfone platforms, decorated with phosphine oxide and methylphosphine oxide donor groups, are described. Coordination chem. of 4, 6- bis(diphenylphosphinoylmethyl) dibenzothiophene (8) , 4, 6- bis(diphenylphosphinoylmethyl) dibenzothiophene- 5, 5- dioxide (9) and 4, 6- bis(diphenylphosphinoyl) dibenzothiophene- 5, 5- dioxide (10) with lanthanide nitrates, Ln(NO3) 3 (H2O) n is outlined, and crystal structure detns. reveal a range of chelation interactions on Ln(III) ions. The HNO3 dependence of the solvent extn. performance of 9 and 10 in 1, 2- dichloroethane for Eu(III) and Am(III) is described and compared against the extn. behavior of related dibenzofuran ligands (2, 3; R = Ph) and n- octyl(phenyl) - N, N- diisobutylcarbamoylmethyl phosphine oxide (4) measured under identical conditions.

• Research Organization: Oak Ridge National Laboratory (ORNL)
• Sponsoring Organization: SC USDOE - Office of Science (SC)
• DOE Contract Number: AC05-00OR22725
• OSTI ID: 1134649
• Journal Information: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 11 Vol. 53; ISSN 0020-1669
• Country of Publication: United States
• Language: English