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Title: Single crystal growth and characterization of the large-unit-cell compound Cu13Ba

Journal Article · · Journal of Alloys and Compounds

Single crystals of Cu13Ba were successfully grown out of Ba–Cu self flux. Temperature dependent magnetization, M (T ), electrical resistivity, ρ(T)ρ(T), and specific heat, Cp(T)Cp(T), data are reported. Isothermal magnetization measurements, M(H)M(H), show clear de Haas-van Alphen oscillations at T = 2 K for applied fields as low as View the MathML sourceμ0H=1T. An anomalous behavior of the magnetic susceptibility is observed up to T ≈ 50 K reflecting the effect of de Haas-van Alphen oscillations at fairly high temperatures. The field- and temperature-dependencies of the magnetization indicate the presence of diluted magnetic impurities with a concentration of the order of 0.01 at.%. Accordingly, the minimum and lower temperature rise observed in the electrical resistivity at and below T = 15 K is attributed to the Kondo-impurity effect.

Research Organization:
Ames Lab., Ames, IA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
DE-AC02-07CH11358
OSTI ID:
1134604
Report Number(s):
IS-J 8225
Journal Information:
Journal of Alloys and Compounds, Vol. 587, Issue 25 February 2014; ISSN 0925-8388
Publisher:
Elsevier
Country of Publication:
United States
Language:
English

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