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Inherently safe in situ uranium recovery

Patent ·
OSTI ID:1130304

An in situ recovery of uranium operation involves circulating reactive fluids through an underground uranium deposit. These fluids contain chemicals that dissolve the uranium ore. Uranium is recovered from the fluids after they are pumped back to the surface. Chemicals used to accomplish this include complexing agents that are organic, readily degradable, and/or have a predictable lifetime in an aquifer. Efficiency is increased through development of organic agents targeted to complexing tetravalent uranium rather than hexavalent uranium. The operation provides for in situ immobilization of some oxy-anion pollutants under oxidizing conditions as well as reducing conditions. The operation also artificially reestablishes reducing conditions on the aquifer after uranium recovery is completed. With the ability to have the impacted aquifer reliably remediated, the uranium recovery operation can be considered inherently safe.

Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Number(s):
8,708,422
Application Number:
13/084,391
OSTI ID:
1130304
Country of Publication:
United States
Language:
English

References (4)

Sorption of Isosaccharinic Acid, a Cellulose Degradation Product, on Cement journal April 1997
Control of pyrite oxidation by phosphate coating journal January 1995
Acidity and Structure of Isosaccharinate in Aqueous Solution: A Nuclear Magnetic Resonance Study journal August 2003
Complexation of Calcium by alpha-Isosaccharinic Acid under Alkaline Conditions. journal January 1999

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