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Conversion of Biomass-Derived Small Oxygenates over HZSM-5 and its Deactivation Mechanism

Journal Article · · Green Chemistry, 16(2):748-760
DOI:https://doi.org/10.1039/c3gc41369a· OSTI ID:1126329
HZSM-5 catalyst deactivation was studied using aqueous feed mixtures containing ethanol, ethanol+ acetic acid, ethanol+ethyl acetate, or ethanol+acetaldehyde in a fixed bed reactor at 360°C and 300psig. Compared to ethanol alone experiment, addition of other oxygenates reduced catalyst life in the order of: ethyl acetate
Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1126329
Report Number(s):
PNNL-SA-97838; BM0101010
Journal Information:
Green Chemistry, 16(2):748-760, Journal Name: Green Chemistry, 16(2):748-760
Country of Publication:
United States
Language:
English

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