A high conductivity oxide–sulfide composite lithium superionic conductor

Rangasamy, Ezhiylmurugan; Sahu, Gayatri; Keum, Jong Kahk; Rondinone, Adam J.; Dudney, Nancy J.; Liang, Chengdu

doi:10.1039/c3ta15223e

Title: A high conductivity oxide–sulfide composite lithium superionic conductor

Journal Article · Tue Jan 14 00:00:00 EST 2014 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/c3ta15223e· OSTI ID:1121804

Rangasamy, Ezhiylmurugan ^[1]; Sahu, Gayatri ^[1]; Keum, Jong Kahk ^[1]; Rondinone, Adam J. ^[1]; Dudney, Nancy J. ^[2]; Liang, Chengdu ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division

We fabricated a hybrid superionic conductor using the space charge effect between the LLZO and LPS interfaces. This space-charge effect resulted in an improvement over the individual bulk conductivities of the two systems. Sample with higher weight fractions of LLZO are limited by the porosity and grain boundary resistance arising from non-sintered membranes. Furthermore, by combining the properties of LLZO and LPS, the high temperature sintering step has been avoided thus facilitating easier materials processing. The interfacial resistances were also measured to be minimal at ambient conditions. Our procedure thus opens a new avenue for improving the ionic conductivity and electrochemical properties of existing solid state electrolytes. High frequency impedance analyses could aid in resolving the ionic conductivity contributions from the space charge layer in the higher conducting composites while mechanical property investigations could illustrate an improvement in the composite electrolyte in comparison with the crystalline LPS membranes.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: AC05-00OR22725

OSTI ID:: 1121804

Journal Information:: Journal of Materials Chemistry. A, Vol. 2, Issue 12; ISSN 2050-7488

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (37)

Mechanical properties of the solid Li-ion conducting electrolyte: Li0.33La0.57TiO3 Cho, Yong-Hun; Wolfenstine, Jeff; Rangasamy, Ezhiylmurugan Journal of Materials Science, Vol. 47, Issue 16 https://doi.org/10.1007/s10853-012-6500-5	journal	April 2012
Conduction Characteristics of the Lithium Iodide-Aluminum Oxide Solid Electrolytes Liang, C. C. Journal of The Electrochemical Society, Vol. 120, Issue 10, p. 1289-1292 https://doi.org/10.1149/1.2403248	journal	October 1973
Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries Lin, Zhan; Liu, Zengcai; Fu, Wujun Angewandte Chemie International Edition, Vol. 52, Issue 29 https://doi.org/10.1002/anie.201300680	journal	June 2013
Nanoionics: ion transport and electrochemical storage in confined systems Maier, J. Nature Materials, Vol. 4, Issue 11, p. 805-815 https://doi.org/10.1038/nmat1513	journal	November 2005
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
High conductivity of dense tetragonal Li₇La₃Zr₂O₁₂ Wolfenstine, Jeff; Rangasamy, Ezhiyl; Allen, Jan L. Journal of Power Sources, Vol. 208, p. 193-196 https://doi.org/10.1016/j.jpowsour.2012.02.031	journal	June 2012
Synthesis of nano-scale fast ion conducting cubic Li ₇ La ₃ Zr ₂ O ₁₂ Sakamoto, Jeff; Rangasamy, Ezhiylmurugan; Kim, Hyunjoung Nanotechnology, Vol. 24, Issue 42 https://doi.org/10.1088/0957-4484/24/42/424005	journal	September 2013
Effect of Interfacial Space-Charge Polarization on the Ionic Conductivity of Composite Electrolytes Dudney, N. J. Journal of the American Ceramic Society, Vol. 68, Issue 10, p. 538-545 https://doi.org/10.1111/j.1151-2916.1985.tb11520.x	journal	October 1985
Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet Ni, Jennifer E.; Case, Eldon D.; Sakamoto, Jeffrey S. Journal of Materials Science, Vol. 47, Issue 23, p. 7978-7985 https://doi.org/10.1007/s10853-012-6687-5	journal	July 2012
High lithium ionic conductivity in the garnet-type oxide Li_7−XLa₃(Zr_2−X, Nb_X)O₁₂ (X=0–2) Ohta, Shingo; Kobayashi, Tetsuro; Asaoka, Takahiko Journal of Power Sources, Vol. 196, Issue 6, p. 3342-3345 https://doi.org/10.1016/j.jpowsour.2010.11.089	journal	March 2011
Effect of substitution (Ta, Al, Ga) on the conductivity of Li₇La₃Zr₂O₁₂ Allen, J. L.; Wolfenstine, J.; Rangasamy, E. Journal of Power Sources, Vol. 206, p. 315-319 https://doi.org/10.1016/j.jpowsour.2012.01.131	journal	May 2012
Progress and prospective of solid-state lithium batteries Takada, Kazunori Acta Materialia, Vol. 61, Issue 3, p. 759-770 https://doi.org/10.1016/j.actamat.2012.10.034	journal	February 2013
Aerosol Deposition of Ceramic Thick Films at Room Temperature: Densification Mechanism of Ceramic Layers Akedo, Jun Journal of the American Ceramic Society, Vol. 89, Issue 6 https://doi.org/10.1111/j.1551-2916.2006.01030.x	journal	June 2006
Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery Liang, Chengdu; Dudney, Nancy J.; Howe, Jane Y. Chemistry of Materials, Vol. 21, Issue 19, p. 4724-4730 https://doi.org/10.1021/cm902050j	journal	October 2009
A lithium superionic conductor Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro Nature Materials, Vol. 10, Issue 9, p. 682-686 https://doi.org/10.1038/nmat3066	journal	July 2011
Inorganic solid Li ion conductors: An overview Knauth, Philippe Solid State Ionics, Vol. 180, Issue 14-16, p. 911-916 https://doi.org/10.1016/j.ssi.2009.03.022	journal	June 2009
First Principles Study of the Li₁₀GeP₂S₁₂ Lithium Super Ionic Conductor Material Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand Chemistry of Materials, Vol. 24, Issue 1, p. 15-17 https://doi.org/10.1021/cm203303y	journal	December 2011
Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification Ohta, N.; Takada, K.; Zhang, L. Advanced Materials, Vol. 18, Issue 17, p. 2226-2229 https://doi.org/10.1002/adma.200502604	journal	September 2006
Advances in Li–S batteries Ji, Xiulei; Nazar, Linda F. Journal of Materials Chemistry, Vol. 20, Issue 44, p. 9821-9826 https://doi.org/10.1039/b925751a	journal	January 2010
Resolving the Grain Boundary and Lattice Impedance of Hot-Pressed Li ₇ La ₃ Zr ₂ O ₁₂ Garnet Electrolytes Tenhaeff, Wyatt E.; Rangasamy, Ezhiyl; Wang, Yangyang ChemElectroChem, Vol. 1, Issue 2 https://doi.org/10.1002/celc.201300022	journal	July 2013
Ionic conduction in space charge regions Maier, Joachim Progress in Solid State Chemistry, Vol. 23, Issue 3 https://doi.org/10.1016/0079-6786(95)00004-E	journal	January 1995
Lithium Superionic Sulfide Cathode for All-Solid Lithium–Sulfur Batteries Lin, Zhan; Liu, Zengcai; Dudney, Nancy J. ACS Nano, Vol. 7, Issue 3, p. 2829-2833 https://doi.org/10.1021/nn400391h	journal	March 2013
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li₇La₃Zr₂O₁₂ Rangasamy, Ezhiyl; Wolfenstine, Jeff; Sakamoto, Jeffrey Solid State Ionics, Vol. 206, p. 28-32 https://doi.org/10.1016/j.ssi.2011.10.022	journal	January 2012
Enhanced ionic conductivity in composite electrolytes Dudney, Nancy J. Solid State Ionics, Vol. 28-30, Issue Part 2, p. 1065-1072 https://doi.org/10.1016/0167-2738(88)90332-3	journal	September 1988
Defect chemistry and ionic conductivity in thin films☆ Maier, J. Solid State Ionics, Vol. 23, Issue 1-2 https://doi.org/10.1016/0167-2738(87)90082-8	journal	March 1987
The effect of 24c-site (A) cation substitution on the tetragonal–cubic phase transition in Li_7−xLa_3−xA_xZr₂O₁₂ garnet-based ceramic electrolyte Rangasamy, Ezhiylmurugan; Wolfenstine, Jeff; Allen, Jan Journal of Power Sources, Vol. 230, p. 261-266 https://doi.org/10.1016/j.jpowsour.2012.12.076	journal	May 2013
Synthesis and high Li-ion conductivity of Ga-stabilized cubic Li7La3Zr2O12 Wolfenstine, Jeff; Ratchford, Joshua; Rangasamy, Ezhiyl Materials Chemistry and Physics, Vol. 134, Issue 2-3 https://doi.org/10.1016/j.matchemphys.2012.03.054	journal	June 2012
Synthesis and structure analysis of tetragonal Li₇La₃Zr₂O₁₂ with the garnet-related type structure Awaka, Junji; Kijima, Norihito; Hayakawa, Hiroshi Journal of Solid State Chemistry, Vol. 182, Issue 8, p. 2046-2052 https://doi.org/10.1016/j.jssc.2009.05.020	journal	August 2009
Space Charge Regions in Solid Two Phase Systems and Their Conduction Contribution - II Contact Equilibrium at the Interface of Two Ionic Conductors and the Related Conductivity Effect Maier, Joachim Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 89, Issue 4, p. 355-362 https://doi.org/10.1002/bbpc.19850890402	journal	April 1985
Space charge regions in solid two-phase systems and their conduction contribution—I. Conductance enhancement in the system ionic conductor-‘inert’ phase and application on AgC1:Al2O3 and AgC1:SiO2 Maier, Joachim Journal of Physics and Chemistry of Solids, Vol. 46, Issue 3 https://doi.org/10.1016/0022-3697(85)90172-6	journal	January 1985
Lithium Ionic Conductor Thio-LISICON: The Li₂S-GeS₂-P₂S₅ System Kanno, Ryoji; Murayama, Masahiro Journal of The Electrochemical Society, Vol. 148, Issue 7, p. A742-A746 https://doi.org/10.1149/1.1379028	journal	January 2001
Anomalous High Ionic Conductivity of Nanoporous β-Li₃PS₄ Liu, Zengcai; Fu, Wujun; Payzant, E. Andrew Journal of the American Chemical Society, Vol. 135, Issue 3, p. 975-978 https://doi.org/10.1021/ja3110895	journal	January 2013
Composite Electrolytes Dudney, N. J. Annual Review of Materials Science, Vol. 19, Issue 1 https://doi.org/10.1146/annurev.ms.19.080189.000535	journal	August 1989
Fast Lithium Ion Conduction in Garnet-Type Li₇La₃Zr₂O₁₂ Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner Angewandte Chemie International Edition, Vol. 46, Issue 41, p. 7778-7781 https://doi.org/10.1002/anie.200701144	journal	October 2007
Al-doped Li₇La₃Zr₂O₁₂ synthesized by a polymerized complex method Jin, Ying; McGinn, Paul J. Journal of Power Sources, Vol. 196, Issue 20, p. 8683-8687 https://doi.org/10.1016/j.jpowsour.2011.05.065	journal	October 2011
Crystal Chemistry and Stability of “Li₇La₃Zr₂O₁₂ ” Garnet: A Fast Lithium-Ion Conductor Geiger, Charles A.; Alekseev, Evgeny; Lazic, Biljana Inorganic Chemistry, Vol. 50, Issue 3, p. 1089-1097 https://doi.org/10.1021/ic101914e	journal	February 2011

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