Highly soluble alkoxide magnesium salts for rechargeable magnesium batteries
Journal Article
·
· Journal of Materials Chemistry. A
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Science Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Science Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
We developed a unique class of air-stable and non-pyrophoric magnesium electrolytes based on alkoxide magnesium compounds. The crystals obtained from this class of electrolytes exhibit a unique structure of tri-magnesium cluster, [Mg3Cl3(OR)2(THF)6]+ [(THF)MgCl3]- . Furthermore we obtained high reversible capacities and good rate capabilities in Mg-Mo6S8 batteries using these new electrolytes at both 20 and 50°C.
- Research Organization:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- AC05-00OR22725
- OSTI ID:
- 1121171
- Journal Information:
- Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 3 Vol. 2; ISSN 2050-7488; ISSN JMCAET
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
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