Evaluation of the Impact of Thin Pours on Saltstone Properties
- Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
The proposed Saltstone Disposal Unit 6 (SDU6) is a larger structure than the SDU4 cells and larger than the disposal units (SDU2, SDU3, and SDU5) currently in use or under construction. The additional capacity provided by SDU6 is desired to reduce life cycle costs and support site accelerated closure goals. The larger size of the planned SDU6 could result in saltstone being placed in thinner lifts as the unit is filled. This study was performed to determine whether thinner layers of saltstone negatively impact the performance of the waste form. A larger number of cold joints could potentially result in increased drying, salt deposition, and surface oxidation. A matrix of samples was prepared to simulate thin pours ranging from 0.5 to 6 inches thick. Each sample was cured for at least 28 days prior to further characterization. Leachability results showed that there is no obvious impact of the number of grout layers on the Leachability Index values for Na and NO3. The concentrations of Cr, NO2, and C2O4 were below detection limits for all of the leachates. No attempt was made to evaluate the oxidation of these samples since no measureable Cr was leached, although this would appear to indicate that Cr in the samples remained reduced for cold joints with surfaces exposed for approximately four days. The results of hydraulic conductivity measurements showed that the number of cold joints in the samples did not have a significant impact on the measured values for the vertical lift orientation (i.e., when the flow path is perpendicular to the cold joints). For the horizontal lift orientation (i.e., when the flow path is parallel to the cold joints), the number of cold joints in the samples also did not appear to have a significant impact on hydraulic conductivity. The measured hydraulic conductivity was faster when the flow path was parallel to the cold joints as compared to when the flow path was perpendicular to the cold joints. Percolation testing showed increased flow when the number of cold joints was increased. Compressive strength testing showed that the maximum load at the onset of cracking was reduced by approximately 26% for those samples that contained cold joints as compared to the monolithic samples. The number of cold joints in the sample had no significant impact on the maximum load prior to cracking. The porosity of the samples was not influenced by cold joints. This result was expected as the porosity is a material property affected by the properties of the components (premix and salt solution) and the water to premix ratio. Overall, the only obvious impact of cold joints in the samples was to significantly increase hydraulic conductivity in the direction parallel to the cold joints. An increasing number of cold joints (thin layers) in the simulated saltstone samples did not exacerbate this effect, nor did it have a negative impact on the Leachability Indices or porosity for surfaces exposed for approximately four days. The presence of a cold joint reduced the compressive strength of the material, although this impact was seen regardless of the number of cold joints in the sample.
- Research Organization:
- Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC09-08SR22470
- OSTI ID:
- 1119573
- Report Number(s):
- SRNL-STI-2012-00522
- Country of Publication:
- United States
- Language:
- English
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