Thermal degradation of new and aged urethane foam and epon 826 epoxy.

Technical Report · Thu Aug 01 04:00:00 EDT 2013

DOI:https://doi.org/10.2172/1115316· OSTI ID:1115316

Kruizenga, Alan Michael ^[1]; Mills, Bernice E. ^[1]

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1. Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Thermal desorption spectroscopy was used to monitor the decomposition as a function of temperature for the foam and epoxy as a function of temperature in the range of 60C to 170C. Samples were studied with one day holds at each of the studied temperatures. Both new (FoamN and EpoxyN) and aged (FoamP and EpoxyP) samples were studied. During these ~10 day experiments, the foam samples lost 11 to 13% of their weight and the EpoxyN lost 10% of its weight. The amount of weight lost was difficult to quantify for EpoxyP because of its inert filler. The onset of the appearance of organic degradation products from FoamP began at 110C. Similar products did not appear until 120C for FoamN, suggesting some effect of the previous decades of storage for FoamP. In the case of the epoxies, the corresponding temperatures were 120C for EpoxyP and 110C for EpoxyN. Suggestions for why the aged epoxy seems more stable than newer sample include the possibility of incomplete curing or differences in composition. Recommendation to limit use temperature to 90-100C for both epoxy and foam.

• Research Organization: Sandia National Laboratories (SNL-CA), Livermore, CA (United States)
• Sponsoring Organization: USDOE National Nuclear Security Administration (NNSA)
• DOE Contract Number: AC04-94AL85000
• OSTI ID: 1115316
• Report Number(s): SAND2013--6519; 481639
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE