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Title: Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

Abstract

Described is a method to make liquid chemicals. The method includes deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be conveted to a mixture of n-butenes. The pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes.

Inventors:
 [1];  [2];  [2]
  1. Verona, WI
  2. Madison, WI
Publication Date:
Research Org.:
Wisconsin Alumni Research Foundation, Madison, WI, USA
Sponsoring Org.:
USDOE
OSTI Identifier:
1113976
Patent Number(s):
8,624,043
Application Number:
13/369,388
Assignee:
Wisconsin Alumni Research Foundation (Madison, WI) CHO
DOE Contract Number:  
FG02-03ER15468
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012 Feb 09
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS

Citation Formats

Dumesic, James A, Ruiz, Juan Carlos Serrano, and West, Ryan M. Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities. United States: N. p., 2014. Web.
Dumesic, James A, Ruiz, Juan Carlos Serrano, & West, Ryan M. Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities. United States.
Dumesic, James A, Ruiz, Juan Carlos Serrano, and West, Ryan M. Tue . "Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities". United States. doi:. https://www.osti.gov/servlets/purl/1113976.
@article{osti_1113976,
title = {Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities},
author = {Dumesic, James A and Ruiz, Juan Carlos Serrano and West, Ryan M},
abstractNote = {Described is a method to make liquid chemicals. The method includes deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be conveted to a mixture of n-butenes. The pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 07 00:00:00 EST 2014},
month = {Tue Jan 07 00:00:00 EST 2014}
}

Patent:

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Works referenced in this record:

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