Criegee intermediates in the indoor environment. New insights

Shallcross, D. E.; Taatjes, C. A.; Percival, C. J.

doi:10.1111/ina.12102

Criegee intermediates in the indoor environment. New insights

Journal Article · Tue Mar 25 00:00:00 EDT 2014 · Indoor Air

DOI:https://doi.org/10.1111/ina.12102· OSTI ID:1111400

Shallcross, D. E. ^[1]; Taatjes, C. A. ^[2]; Percival, C. J. ^[3]

School of Chemistry, Cantock's Close, University of Bristol, Bristol UK
School of Chemistry, Cantock's Close, University of Bristol, Bristol UK; Combustion Research Facility, Sandia National Laboratories, Livermore CA USA
The Centre for Atmospheric Science, The School of Earth, Atmospheric and Environmental Science, The University of Manchester, Manchester UK

Criegee intermediates are formed in the ozonolysis of alkenes and play an important role in indoor chemistry, notably as a source of OH radicals. Recent studies have shown that these Criegee intermediates react very quickly with NO₂, SO₂, and carbonyls, and in this study, steady-state calculations are used to inspect the potential impact of these data on indoor chemistry. It is shown that these reactions could accelerate NO₃ formation and SO₂ removal in the indoor environment significantly. In addition, reaction between Criegee intermediates and halogenated carbonyls could provide a significant loss process indoors, where currently one does not exist.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1111400

Report Number(s):: SAND--2013-5105J; 456549

Journal Information:: Indoor Air, Journal Name: Indoor Air Journal Issue: 5 Vol. 24; ISSN 1600-0668

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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