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Title: Color stable phosphors for LED lamps and methods for preparing them

Patent ·
OSTI ID:1109086

An LED lamp includes a light source configured to emit radiation with a peak intensity at a wavelength between about 250 nm and about 550 nm; and a phosphor composition configured to be radiationally coupled to the light source. The phosphor composition includes particles of a phosphor of formula I, said particles having a coating composition disposed on surfaces thereof; ((Sr.sub.1-zM.sub.z).sub.1-(x+w)A.sub.wCe.sub.x).sub.3(Al.sub.1-ySi.sub.y-)O.sub.4+y+3(x-w)F.sub.1-y-3(x-w) I wherein the coating composition comprises a material selected from aluminum oxide, magnesium oxide, calcium oxide, barium oxide, strontium oxide, zinc oxide, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, barium hydroxide, strontium hydroxide, zinc hydroxide, aluminum phosphate, magnesium phosphate, calcium phosphate, barium phosphate, strontium phosphate, and combinations thereof; and A is Li, NA, K, or Rb, or a combination thereof; M is Ca, Ba, Mg, Zn, or a combination thereof; and 0<x.ltoreq.1.10, 0.ltoreq.y.ltoreq.0.5, 0.ltoreq.z.ltoreq.0.5, 0.ltoreq.x.ltoreq.x.

Research Organization:
General Electric Company, Niskayuna, NY, USA
Sponsoring Organization:
USDOE
DOE Contract Number:
FC26-06NT42934
Assignee:
General Electric Company (Niskayuna, NY)
Patent Number(s):
8,593,062
Application Number:
13/080,099
OSTI ID:
1109086
Country of Publication:
United States
Language:
English

References (5)

Light-emitting device with coated phosphor patent April 2007
Surface Modification of SrAl2O4:Eu2+, Dy3+ Phosphors Using Silica Encapsulation journal October 2008
Y2O2S:Eu Red Phosphor Powders Coated with Silica journal August 2000
Luminescent material coated with a protective layer patent July 2002
Coated phosphor filler and a method of forming the coated phosphor filler patent May 2004