Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Magnetic order tuned by Cu substitution in Fe1.1–zCuzTe

Journal Article · · Physical Review. B, Condensed Matter and Materials Physics
We study the effects of Cu substitution in Fe₁.₁Te, the nonsuperconducting parent compound of the iron-based superconductor, Fe₁₊yTe₁₋xSex, utilizing neutron scattering techniques. It is found that the structural and magnetic transitions, which occur at ~60 K without Cu, are monotonically depressed with increasing Cu content. By 10% Cu for Fe, the structural transition is hardly detectable, and the system becomes a spin glass below 22 K, with a slightly incommensurate ordering wave vector of (0.5–δ, 0, 0.5) with δ being the incommensurability of 0.02, and correlation length of 12 Å along the a axis and 9 Å along the c axis. With 4% Cu, both transition temperatures are at 41 K, though short-range incommensurate order at (0.42, 0, 0.5) is present at 60 K. With further cooling, the incommensurability decreases linearly with temperature down to 37 K, below which there is a first-order transition to a long-range almost-commensurate antiferromagnetic structure. A spin anisotropy gap of 4.5 meV is also observed in this compound. Our results show that the weakly magnetic Cu has a large effect on the magnetic correlations; it is suggested that this is caused by the frustration of the exchange interactions between the coupled Fe spins.
Sponsoring Organization:
USDOE
OSTI ID:
1103681
Alternate ID(s):
OSTI ID: 1081932
Journal Information:
Physical Review. B, Condensed Matter and Materials Physics, Journal Name: Physical Review. B, Condensed Matter and Materials Physics Journal Issue: 2 Vol. 86; ISSN 1098-0121; ISSN PRBMDO
Publisher:
American Physical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (51)

Structure antiferroma gnetique de Fe1. 125Te accompagnee d'une deformation monoclinique journal March 1975
Neutron studies of the iron-based family of high TC magnetic superconductors journal May 2009
Evolution of two-step structural phase transition in Fe1+dTe detected by low-temperature x-ray diffraction journal June 2012
From (π,0) magnetic order to superconductivity with (π,π) magnetic resonance in Fe1.02Te1−xSex journal July 2010
Kinetic frustration and the nature of the magnetic and paramagnetic states in iron pnictides and iron chalcogenides journal September 2011
A universal relationship between magnetic resonance and superconducting gap in unconventional superconductors journal October 2009
Evolution of spin excitations into the superconducting state in FeTe1−xSex journal January 2010
Superconductivity in the PbO-type structure  -FeSe journal September 2008
The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides journal October 2010
Interplay between magnetism and superconductivity in iron-chalcogenide superconductors: crystal growth and characterizations journal September 2011
Gap symmetry and structure of Fe-based superconductors journal October 2011
The metal–insulator transition in Fe 1.01− x Cu x Se journal July 2009
Effects of disorder in FeSe: an ab initio study journal March 2010
Magnetism in Fe-based superconductors journal April 2010
Density functional study of FeS, FeSe, and FeTe: Electronic structure, magnetism, phonons, and superconductivity journal October 2008
Density functional study of excess Fe in Fe 1 + x Te : Magnetism and doping journal January 2009
First-order magnetic and structural phase transitions in Fe 1 + y Se x Te 1 − x journal February 2009
Bulk superconductivity at 14 K in single crystals of Fe 1 + y Te x Se 1 − x journal March 2009
Microscopic origin of magnetism and magnetic interactions in ferropnictides journal June 2009
Pnictogen height as a possible switch between high- T c nodeless and low- T c nodal pairings in the iron-based superconductors journal June 2009
Short-range incommensurate magnetic order near the superconducting phase boundary in Fe 1 + δ Te 1 − x Se x journal September 2009
Kinetic magnetism and orbital order in iron telluride journal December 2009
From antiferromagnetism to superconductivity in Fe 1 + y Te 1 − x Se x ( 0 ≤ x ≤ 0.20 ) : Neutron powder diffraction analysis journal March 2010
Effect of magnetic field on the spin resonance in FeTe 0.5 Se 0.5 as seen via inelastic neutron scattering journal March 2010
Doping-driven structural phase transition and loss of superconductivity in M x Fe 1 − x Se δ ( M = Mn ,   Cu ) journal September 2010
Disappearance of static magnetic order and evolution of spin fluctuations in Fe 1 + δ Se x Te 1 − x journal September 2010
Strong correlations and spin-density-wave phase induced by a massive spectral weight redistribution in α -Fe 1.06 Te journal October 2010
Magnetoelastic effects in iron telluride journal March 2011
X-ray diffuse scattering study of local distortions in Fe 1 + x Te induced by excess Fe journal May 2011
Interstitial iron tuning of the spin fluctuations in the nonsuperconducting parent phase Fe 1 + x Te journal July 2011
Magnetic-crystallographic phase diagram of the superconducting parent compound Fe 1 + x Te journal August 2011
Effect of the isoelectronic substitution of Sb for As on the magnetic and structural properties of LaFe(As 1 − x Sb x )O journal September 2011
Magnetic properties of spin-diluted iron pnictides from μ SR and NMR in LaFe 1 − x Ru x AsO journal February 2012
Continuous magnetic and structural phase transitions in Fe 1 + y Te journal February 2012
Spin fluctuations and superconductivity in powders of Fe 1 + x Te 0.7 Se 0.3 as a function of interstitial iron concentration journal March 2012
Competition between commensurate and incommensurate magnetic ordering in Fe 1 + y Te journal April 2012
Unconventional Superconductivity with a Sign Reversal in the Order Parameter of LaFeAsO 1 − x F x journal July 2008
Unconventional Pairing Originating from the Disconnected Fermi Surfaces of Superconducting LaFeAsO 1 − x F x journal August 2008
First-Principles Calculations of the Electronic Structure of Tetragonal α -FeTe and α -FeSe Crystals: Evidence for a Bicollinear Antiferromagnetic Order journal April 2009
Tunable ( δ π , δ π )-Type Antiferromagnetic Order in α -Fe(Te,Se) Superconductors journal June 2009
Fermi Surface Topology and Low-Lying Quasiparticle Dynamics of Parent Fe 1 + x Te / Se Superconductor journal July 2009
Spin Gap and Resonance at the Nesting Wave Vector in Superconducting FeSe 0.4 Te 0.6 journal August 2009
Chalcogen-Height Dependent Magnetic Interactions and Magnetic Order Switching in FeSe x Te 1 − x journal February 2010
Orbital-Fluctuation-Mediated Superconductivity in Iron Pnictides: Analysis of the Five-Orbital Hubbard-Holstein Model journal April 2010
Unified Picture for Magnetic Correlations in Iron-Based Superconductors journal September 2010
Unconventional Temperature Enhanced Magnetism in Fe 1.1 Te journal November 2011
Friedel-Like Oscillations from Interstitial Iron in Superconducting Fe 1 + y Te 0.62 Se 0.38 journal March 2012
Magnetic Neutron Scattering in Hole-Doped Cuprate Superconductors journal November 2006
Review of Fe Chalcogenides as the Simplest Fe-Based Superconductor journal October 2010
Investigation of the Spin-Glass Regime between the Antiferromagnetic and Superconducting Phases in Fe 1+ y Se x Te 1- x journal November 2010
Theory of magnetic order in Fe 1+ y Te 1- x Se x journal June 2009

Similar Records

Magnetic orders tuned by Cu substitution in Fe1.1 zCuzTe
Journal Article · Sat Dec 31 23:00:00 EST 2011 · Physical Review B · OSTI ID:1081932

Spin-reorientation and weak ferromagnetism in antiferromagnetic TbMn{sub 0.5}Fe{sub 0.5}O{sub 3}
Journal Article · Thu May 07 00:00:00 EDT 2015 · Journal of Applied Physics · OSTI ID:22402978

Neutron inelastic scattering investigation of the magnetic excitations in Cu{sub 2}Te{sub 2}O{sub 5}X{sub 2} (X=Br,Cl)
Journal Article · Wed Jun 01 00:00:00 EDT 2005 · Physical Review. B, Condensed Matter and Materials Physics · OSTI ID:20719056

Related Subjects