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Mesophase pitch-based carbon fiber for improved inflammability of CFRP

Book ·
OSTI ID:109726
;  [1];  [2]
  1. Mitsubishi Chemical Corp. Functional Material Co., Tokyo (Japan). Carbon Fiber and Advanced Materials Composite Div.
  2. Mitsubishi Chemical Corp., Yokohama (Japan). Advanced Composite Materials Lab.

Carbon Fiber Reinforced Plastics (CFRP) are extensively used because of their favorable physical properties such as high strength-to-weight ratio and small thermal expansion. However, flammability of CFRP has limited their application especially in the transportation and industrial field. Exposed to flame, CFRP laminates made of PAN-based carbon fibers burst into flame in short time, while CFRP laminates made from mesophase pitch-based carbon fibers don`t burst into flame. This paper describes the experimental results of local heating test by gas burner. When the flame temperature was 1,000 C, a CFRP laminate made from PAN-based carbon fiber burned within 40 sec. Under the same condition, a CFRP laminate made from mesophase pitch-based carbon fiber didn`t burn in 10 min. The matrix resin of both laminates was 250 F curable epoxy resin. This behavior mainly depends upon the thermal conductivity of the carbon fibers. The mesophase pitch-based carbon fibers have high thermal conductivity, so they can diffuse thermal energy and lower laminate surface temperature. On the other hand, PAN-based carbon fibers have low thermal conductivity, so they can`t diffuse thermal energy enough, and the laminates made from them burn easily. Mechanical properties of CFRP during local heating test in comparison with Aluminum plate are also discussed.

OSTI ID:
109726
Report Number(s):
CONF-950521--; ISBN 1-56676-313-4
Country of Publication:
United States
Language:
English