Metal-organic frameworks for Xe/Kr separation

Ryan, Patrick J.; Farha, Omar K.; Broadbelt, Linda J.; Snurr, Randall Q.; Bae, Youn-Sang

Metal-organic frameworks for Xe/Kr separation

Patent · Tue Aug 27 04:00:00 EDT 2013

OSTI ID:1093277

Ryan, Patrick J.; Farha, Omar K.; Broadbelt, Linda J.; Snurr, Randall Q.; Bae, Youn-Sang

Metal-organic framework (MOF) materials are provided and are selectively adsorbent to xenon (Xe) over another noble gas such as krypton (Kr) and/or argon (Ar) as a result of having framework voids (pores) sized to this end. MOF materials having pores that are capable of accommodating a Xe atom but have a small enough pore size to receive no more than one Xe atom are desired to preferentially adsorb Xe over Kr in a multi-component (Xe--Kr mixture) adsorption method. The MOF material has 20% or more, preferably 40% or more, of the total pore volume in a pore size range of 0.45-0.75 nm which can selectively adsorb Xe over Kr in a multi-component Xe--Kr mixture over a pressure range of 0.01 to 1.0 MPa.

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Research Organization:: Northwestern University, Evanston, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-03ER15457

Assignee:: Northwestern University (Evanston, IL)

Patent Number(s):: 8,518,153

Application Number:: 13/199,043

OSTI ID:: 1093277

Country of Publication:: United States

Language:: English

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