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Porphyrin coordination polymer nanospheres and nanorods

Patent ·
OSTI ID:1092944

A porphyrin coordination polymer nanostructure comprising a network of pyridyl porphyrin molecules and coordinating metal ions coordinatively bound through the pyridyl groups. In some embodiments, the porphyrins are metalloporphyrins. A variety of nanostructures are formed by the network polymer, including nanospheres, polygonal nanostructures, nanorods, and nanofibers, depending on a variety of factors including coordination metal ion, porphyrin type, metal of the metalloporphyrin, and degree of agitation during nanostructure formation. Reduction of coordinating metal ions may be used to form metal nanoparticles on the coordination polymer nanostructure.

Research Organization:
SNL-A (Sandia National Laboratories, Albuquerque, NM (United States))
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Number(s):
8,530,614
Application Number:
13/664,170
OSTI ID:
1092944
Country of Publication:
United States
Language:
English

References (3)

A Porphyrin Prism: Structural Switching Triggered by Guest Inclusion journal May 2001
Topics in Stereochemistry book April 2006
Self-Metallization of Photocatalytic Porphyrin Nanotubes journal December 2004

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