Method for determining processability of a hydrocarbon containing feedstock

Schabron, John F.; Rovani, Jr., Joseph F.

Method for determining processability of a hydrocarbon containing feedstock

Patent · Tue Sep 10 00:00:00 EDT 2013

OSTI ID:1092940

Schabron, John F.; Rovani, Jr., Joseph F.

Disclosed herein is a method involving the steps of (a) precipitating an amount of asphaltenes from a liquid sample of a first hydrocarbon-containing feedstock having solvated asphaltenes therein with one or more first solvents in a column; (b) determining one or more solubility characteristics of the precipitated asphaltenes; (c) analyzing the one or more solubility characteristics of the precipitated asphaltenes; and (d) correlating a measurement of feedstock reactivity for the first hydrocarbon-containing feedstock sample with a mathematical parameter derived from the results of analyzing the one or more solubility characteristics of the precipitated asphaltenes.

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Research Organization:: NETL (National Energy Technology Laboratory, Pittsburgh, PA, and Morgantown, WV (United States))

Sponsoring Organization:: USDOE

DOE Contract Number:: FC26-98FT40322

Assignee:: The University of Wyoming Research Corporation (Laramie, WY)

Patent Number(s):: 8,530,240

Application Number:: 13/490,307

OSTI ID:: 1092940

Country of Publication:: United States

Language:: English

References (48)

Some factors affecting the solubility of polymers Small, P. A. Journal of Applied Chemistry, Vol. 3, Issue 2 https://doi.org/10.1002/jctb.5010030205	journal	February 1953
Precipitation-redissolution liquid chromatography of styrene-ethyl acrylate copolymers Chiantore, Oscar; Simonelli, Alessandra Polymer Engineering & Science, Vol. 39, Issue 8 https://doi.org/10.1002/pen.11527	journal	August 1999
Petroleum Processing Overview Robinson, Paul R. Practical Advances in Petroleum Processing, p. 1-78 https://doi.org/10.1007/978-0-387-25789-1_1	book	December 2005
Kinetic models for the thermal cracking of Athabasca bitumen Phillips, Colin R.; Haidar, Nagib I.; Poon, Yiu C. Fuel, Vol. 64, Issue 5, p. 678-691 https://doi.org/10.1016/0016-2361(85)90055-9	journal	May 1985
Characteristic changes of asphaltenes during visbreaking of North Gujarat short residue Singh, I. D.; Kothiyal, V.; Ramaswamy, V. Fuel, Vol. 69, Issue 3, p. 289-292 https://doi.org/10.1016/0016-2361(90)90088-8	journal	March 1990
Thermal cracking of petroleum residues: 1. Kinetic analysis of the reaction Del Bianco, A.; Panariti, N.; Anelli, M. Fuel, Vol. 72, Issue 1, p. 75-80 https://doi.org/10.1016/0016-2361(93)90379-G	journal	January 1993
Aggregation of asphaltenes as determined by calorimetry Andersen, Simon Ivar; Birdi, Kulbir S. Journal of Colloid and Interface Science, Vol. 142, Issue 2, p. 497-502 https://doi.org/10.1016/0021-9797(91)90079-N	journal	March 1991
Analysis of petroleum fractions by TLC-FID: applications to petroleum reservoir description Karlsen, Dag A.; Larter, Steve R. Organic Geochemistry, Vol. 17, Issue 5, p. 603-617 https://doi.org/10.1016/0146-6380(91)90004-4	journal	January 1991
Molecular weight polarity map for residua pyrolysis Schabron, J. Fuel, Vol. 80, Issue 4 https://doi.org/10.1016/S0016-2361(00)00100-9	journal	March 2001
Non-pyrolytic heat induced deposition from heavy oils Schabron, J. F.; Pauli, A. T.; Rovani, J. F. Fuel, Vol. 80, Issue 7, p. 919-928 https://doi.org/10.1016/S0016-2361(00)00205-2	journal	May 2001
Predicting coke formation tendencies Schabron, John F.; Pauli, Adam T.; Rovani, Joseph F. Fuel, Vol. 80, Issue 10, p. 1435-1446 https://doi.org/10.1016/S0016-2361(01)00012-6	journal	August 2001
Residua coke formation predictability maps Schabron, John F.; Pauli, Adam T.; Rovani Jr., Joseph F. Fuel, Vol. 81, Issue 17, p. 2227-2240 https://doi.org/10.1016/S0016-2361(02)00153-9	journal	December 2002
Acoustic method for measuring asphaltene flocculation in crude oils Carrier, H.; Plantier, F.; Daridon, J-L. Journal of Petroleum Science and Engineering, Vol. 27, Issue 3-4, p. 111-117 https://doi.org/10.1016/S0920-4105(00)00052-8	journal	September 2000
Initial studies using ultrasonic spectroscopy for monitoring changes in residua with pyrolysis Schabron, John F.; Rovani, Joseph F.; Pauli, A. Troy Fuel, Vol. 85, Issue 14-15, p. 2093-2105 https://doi.org/10.1016/j.fuel.2006.04.003	journal	October 2006
On-column precipitation and re-dissolution of asphaltenes in petroleum residua Schabron, John F.; Rovani, Joseph F. Fuel, Vol. 87, Issue 2, p. 165-176 https://doi.org/10.1016/j.fuel.2007.04.024	journal	February 2008
TLC–FID (Iatroscan) analysis of heavy oil and tar sand samples Jiang, Chunqing; Larter, Steve R.; Noke, Kimberley J. Organic Geochemistry, Vol. 39, Issue 8, p. 1210-1214 https://doi.org/10.1016/j.orggeochem.2008.01.013	journal	August 2008
Automated liquid chromatographic compound class group-type separation of crude oils and bitumens using chemically bonded silica-NH2 Grizzle, Patrick L.; Sablotny, Donna M. Analytical Chemistry, Vol. 58, Issue 12 https://doi.org/10.1021/ac00125a009	journal	October 1986
Separation of solvent-refined coal into solvent-derived fractions Boduszynski, M. M.; Hurtubise, R. J.; Silver, H. F. Analytical Chemistry, Vol. 54, Issue 3 https://doi.org/10.1021/ac00240a007	journal	March 1982
Preparative hydrocarbon group type determination by automated medium pressure liquid chromatography Radke, Matthias.; Willsch, Helmut.; Welte, Dietrich H. Analytical Chemistry, Vol. 52, Issue 3 https://doi.org/10.1021/ac50053a009	journal	March 1980
Composition of asphalt based on generic fractionation, using solvent deasphaltening, elution-adsorption chromatography, and densimetric characterization Corbett, Luke W. Analytical Chemistry, Vol. 41, Issue 4 https://doi.org/10.1021/ac60273a004	journal	April 1969
Ion-exchange, coordination, and adsorption chromatographic separation of heavy-end petroleum distillates Jewell, D. M.; Weber, J. H.; Bunger, J. W. Analytical Chemistry, Vol. 44, Issue 8 https://doi.org/10.1021/ac60316a003	journal	July 1972
Equilibria in Non-electrolyte Solutions in Relation to the Vapor Pressures and Densities of the Components. Scatchard, George. Chemical Reviews, Vol. 8, Issue 2 https://doi.org/10.1021/cr60030a010	journal	April 1931
Solubility parameters Barton, Allan F. M. Chemical Reviews, Vol. 75, Issue 6 https://doi.org/10.1021/cr60298a003	journal	December 1975
Composition of heavy petroleums. 1. Molecular weight, hydrogen deficiency, and heteroatom concentration as a function of atmospheric equivalent boiling point up to 1400.degree.F (760.degree.C) Boduszynski, Mieczyslaw M. Energy & Fuels, Vol. 1, Issue 1 https://doi.org/10.1021/ef00001a001	journal	January 1987
Dynamics of Bitumen Fractions by Thin-Layer Chromatography/Flame Ionization Detection Masson, J-F.; Price, Terry; Collins, Peter Energy & Fuels, Vol. 15, Issue 4 https://doi.org/10.1021/ef0100247	journal	July 2001
Determination of Saturate, Aromatic, Resin, and Asphaltenic (SARA) Components in Crude Oils by Means of Infrared and Near-Infrared Spectroscopy Aske, Narve; Kallevik, Harald; Sjöblom, Johan Energy & Fuels, Vol. 15, Issue 5 https://doi.org/10.1021/ef010088h	journal	September 2001
Rapid and Accurate SARA Analysis of Medium Gravity Crude Oils Fan, Tianguang; Buckley, Jill S. Energy & Fuels, Vol. 16, Issue 6 https://doi.org/10.1021/ef0201228	journal	November 2002
Asphaltene Determinator Method for Automated On-Column Precipitation and Redissolution of Pericondensed Aromatic Asphaltene Components ^† Schabron, John F.; Rovani, Joseph F.; Sanderson, Mark M. Energy & Fuels, Vol. 24, Issue 11 https://doi.org/10.1021/ef100822f	journal	November 2010
Adsorption of Athabasca Vacuum Residues and Their Visbroken Products over Macroporous Solids: Influence of Their Molecular Characteristics Lopez-Linares, Francisco; Carbognani, Lante; Hassan, Azfar Energy & Fuels, Vol. 25, Issue 9 https://doi.org/10.1021/ef201047z	journal	September 2011
Asphaltene Chemical Characterization as a Function of Solubility: Effects on Stability and Aggregation Rogel, Estrella; Ovalles, Cesar; Moir, Michael Energy & Fuels, Vol. 26, Issue 5 https://doi.org/10.1021/ef2013979	journal	December 2011
Characterization of Heavy Crude Oils, Their Fractions, and Hydrovisbroken Products by the Asphaltene Solubility Fraction Method Ovalles, Cesar; Rogel, Estrella; Moir, Michael Energy & Fuels, Vol. 26, Issue 1 https://doi.org/10.1021/ef201499f	journal	December 2011
Waxphaltene Determinator Method for Automated Precipitation and Redissolution of Wax and Asphaltene Components Schabron, John F.; Rovani, Joseph F.; Sanderson, Mark M. Energy & Fuels, Vol. 26, Issue 4 https://doi.org/10.1021/ef300184s	journal	March 2012
Sediment Formation in Residue Hydroconversion Processes and Its Correlation to Asphaltene Behavior Rogel, Estrella; Ovalles, Cesar; Pradhan, Ajit Energy & Fuels, Vol. 27, Issue 11 https://doi.org/10.1021/ef401614a	journal	October 2013
Issues with Comparing SARA Methodologies Kharrat, Abdel M.; Zacharia, Jose; Cherian, V. John Energy & Fuels, Vol. 21, Issue 6 https://doi.org/10.1021/ef700393a	journal	November 2007
Determination of Asphaltenes in Crude Oil and Petroleum Products by the on Column Precipitation Method Rogel, Estrella; Ovalles, Cesar; Moir, Michael E. Energy & Fuels, Vol. 23, Issue 9 https://doi.org/10.1021/ef900358q	journal	September 2009
A phase-separation kinetic model for coke formation Wiehe, Irwin A. Industrial & Engineering Chemistry Research, Vol. 32, Issue 11 https://doi.org/10.1021/ie00023a001	journal	November 1993
Influence of Vine Vigor on Grape ( Vitis vinifera L. Cv. Pinot Noir) Anthocyanins. 2. Anthocyanins and Pigmented Polymers in Wine Cortell, Jessica M.; Halbleib, Michael; Gallagher, Andrew V. Journal of Agricultural and Food Chemistry, Vol. 55, Issue 16 https://doi.org/10.1021/jf070196n	journal	August 2007
456. A new chromatographic procedure and its application to high polymers Baker, C. A.; Williams, R. J. P. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9560002352	journal	January 1956
Two-Dimensional Solubility Parameter Mapping of Heavy oils Wiehe, Irwin A. Fuel Science and Technology International, Vol. 14, Issue 1-2 https://doi.org/10.1080/08843759608947572	journal	January 1996
The Solubility and Three-Dimensional Structure of Asphaltenes Schabron, John F.; Speight, James G. Petroleum Science and Technology, Vol. 16, Issue 3-4 https://doi.org/10.1080/10916469808949788	journal	March 1998
Relationships Between Asphaltenes, Heithaus Compatibility Parameters, and Asphalt Viscosity Pauli, Adam T.; Branthaver, Jan F. Petroleum Science and Technology, Vol. 16, Issue 9-10 https://doi.org/10.1080/10916469808949827	journal	October 1998
Reactivity of Fluid Catalytic Cracking Feedstocks as a Function of Reactive Hydrogen Content Mariaca-Domínguez, E.; Maya-Yescas, R.; Rodríguez-Salomón, S. Petroleum Science and Technology, Vol. 22, Issue 1-2 https://doi.org/10.1081/LFT-120028519	journal	January 2004
Viscosity/Concentration Relationships for Emulsions Pal, Rajinder; Rhodes, Edward Journal of Rheology, Vol. 33, Issue 7 https://doi.org/10.1122/1.550044	journal	October 1989
Office No authors listed working@office, Vol. 13, Issue 12, p. 16-19 https://doi.org/10.1365/s35131-012-0338-7	journal	November 2012
Petroleum Processing Efficiency Improvement Schabron, John; Rovani, Joseph; Sanderson, Mark https://doi.org/10.2172/1050225	report	August 2012
Energy and Environmental Profile of the U.S. Petroleum Refining Industry Pellegrino, Joan; Brueske, Sabine; Carole, Tracy Report - US Department of Energy https://doi.org/10.2172/1218665	report	November 2007
Petroleum Residua Solubility Parameter/Polarity Map: Stability Studies of Residua Pyrolysis Schabron, John F.; Pauli, A. Troy; Rovani Jr., Joseph F. https://doi.org/10.2172/778911	report	April 1999
Studies in Petroleum Composition Development of a Compositional Map for Various Feedstocks Long, R. B.; Speight, J. G. Revue de l'Institut Français du Pétrole, Vol. 44, Issue 2 https://doi.org/10.2516/ogst:1989013	journal	March 1989

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