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Title: Gas sensor incorporating a porous framework

Patent ·
OSTI ID:1087899

The disclosure provides sensor for gas sensing including CO.sub.2 gas sensors comprising a porous framework sensing area for binding an analyte gas.

Research Organization:
University of California (Oakland, CA)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-08ER15935
Assignee:
The Regents of the University of California (Oakland, CA); BASF SE (Ludwigshafen, DE)
Patent Number(s):
8,480,955
Application Number:
13/142,564
OSTI ID:
1087899
Country of Publication:
United States
Language:
English

References (174)

Covalently linked organic frameworks and polyhedra patent-application July 2006
Supertetrahedral Sulfide Crystals with Giant Cavities and Channels journal February 1999
Shaped bodies containing metal-organic frameworks patent-application December 2003
Synthesis and Structure of Chemically Stable Metal−Organic Polyhedra journal September 2009
High H2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites journal July 2005
Strategies for Hydrogen Storage in Metal-Organic Frameworks journal July 2005
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application December 2004
Tailored Porous Materials journal October 1999
Shaped bodies containing metal-organic frameworks patent May 2005
Modular Chemistry: Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal−Organic Carboxylate Frameworks journal April 2001
A Nearly Planar Water Sheet Sandwiched between Strontium−Imidazolium Carboxylate Coordination Polymers journal July 2005
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application January 2003
Exceptional H2 Saturation Uptake in Microporous Metal−Organic Frameworks journal March 2006
A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks journal August 2010
Reversible oxygen sorbent compositions patent May 1993
Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals patent-application November 2004
Process for preparing an organometallic framework material patent-application July 2005
Reticular Chemistry of Metal–Organic Polyhedra journal June 2008
Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(II)−Benzenetricarboxylate Network journal March 1997
Hydrogen Storage in Microporous Metal-Organic Frameworks journal May 2003
Assembly of Metal−Organic Frameworks from Large Organic and Inorganic Secondary Building Units:  New Examples and Simplifying Principles for Complex Structures journal August 2001
Ultrahigh Porosity in Metal-Organic Frameworks journal July 2010
Open-Framework Solids with Diamond-Like Structures Prepared from Clusters and Metal-Organic Building Blocks journal January 1994
Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels journal October 1995
Synthetic Strategies, Structure Patterns, and Emerging Properties in the Chemistry of Modular Porous Solids journal August 1998
Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid journal January 1996
Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
  • Côté, Adrien P.; El-Kaderi, Hani M.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 129, Issue 43, p. 12914-12915 https://doi.org/10.1021/ja0751781
journal October 2007
Design of New Materials for Methane Storage journal March 2004
Designing Porosity in Coordination Solids book January 1997
T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO3 journal January 1996
Azulene based metal–organic frameworks for strong adsorption of H2 journal January 2010
Establishing Microporosity in Open Metal−Organic Frameworks:  Gas Sorption Isotherms for Zn(BDC) (BDC = 1,4-Benzenedicarboxylate) journal August 1998
Metal–organic Frameworks: A tale of two entanglements journal February 2007
Method of storing, uptaking, releasing of gases by novel framework materials patent August 2005
Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature patent September 2010
Transformation of Germanium Dioxide to Microporous Germanate 4-Connected Nets journal October 1998
Mesh-Adjustable Molecular Sieve patent-application August 2008
Hydrogen Sorption in Functionalized Metal−Organic Frameworks
  • Rowsell, Jesse L. C.; Millward, Andrew R.; Park, Kyo Sung
  • Journal of the American Chemical Society, Vol. 126, Issue 18, p. 5666-5667 https://doi.org/10.1021/ja049408c
journal May 2004
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent April 2007
Conversion of hydrogen-bonded manganese(II) and zinc(II) squarate (C4O42–) molecules, chains and sheets to three-dimensional cage networks journal January 1995
A metal–organic framework replete with ordered donor–acceptor catenanes journal January 2010
Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal−Organic Frameworks and Polyhedra journal September 2008
Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0 journal September 2008
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent-application January 2005
Reticular Chemistry and Metal-Organic Frameworks for Clean Energy journal September 2009
Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals patent January 2010
A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
  • Uribe-Romo, Fernando J.; Hunt, Joseph R.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 131, Issue 13, p. 4570-4571 https://doi.org/10.1021/ja8096256
journal April 2009
Porous Germanates:  Synthesis, Structure, and Inclusion Properties of Ge7O14.5F2·[(CH3)2NH2]3(H2O)0.86 journal August 1998
Selective binding and removal of guests in a microporous metal–organic framework journal December 1995
Advances in the chemistry of metal–organic frameworks journal January 2002
Crystal Growth of Extended Solids by Nonaqueous Gel Diffusion journal May 1997
Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units journal February 2005
Three-periodic nets and tilings: regular and quasiregular nets journal December 2002
Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties journal March 2009
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application September 2005
Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine journal October 2010
Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
  • Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael
  • Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283 https://doi.org/10.1039/b817735j
journal January 2009
High gas adsorption in a microporous metal-organic framework with open-metal sites patent-application November 2006
Exceptional ammonia uptake by a covalent organic framework journal February 2010
The pervasive chemistry of metal–organic frameworks journal January 2009
Metal-organic framework materials for gaseous hydrocarbon storage patent March 2008
Design and synthesis of an exceptionally stable and highly porous metal-organic framework journal November 1999
CHEMICAL FRAMEWORK COMPOSITIONS AND METHODS OF USE patent-application June 2011
Metal-organic frameworks—New materials for hydrogen storage journal April 2007
Isoreticular Metalation of Metal−Organic Frameworks
  • Doonan, Christian J.; Morris, William; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 131, Issue 27, p. 9492-9493 https://doi.org/10.1021/ja903251e
journal July 2009
Synthesis, Structure, and Carbon Dioxide Capture Properties of Zeolitic Imidazolate Frameworks journal January 2010
Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores journal February 2001
Coordinatively Unsaturated Metal Centers in the Extended Porous Framework of Zn3(BDC)3·6CH3OH (BDC = 1,4-Benzenedicarboxylate) journal March 1998
Polycatenation, polythreading and polyknotting in coordination network chemistry journal November 2003
What do we know about three-periodic nets? journal August 2005
Crystalline Covalent Organic Frameworks with Hydrazone Linkages
  • Uribe-Romo, Fernando J.; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 133, Issue 30, p. 11478-11481 https://doi.org/10.1021/ja204728y
journal August 2011
Raman spectra of hydrogen and deuterium adsorbed on a metal–organic framework journal August 2005
Porous, Crystalline, Covalent Organic Frameworks journal November 2005
Raman Spectroscopic Investigation of CH4 and N2 Adsorption in Metal−Organic Frameworks journal July 2007
A Crystalline Mesoporous Coordination Copolymer with High Microporosity journal January 2008
Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction journal January 2006
Zeolite A imidazolate frameworks journal May 2007
Impact of Preparation and Handling on the Hydrogen Storage Properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5) journal November 2007
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent March 2007
Process for preparing and organometallic framework material patent August 2008
Three-periodic nets and tilings: edge-transitive binodal structures journal August 2006
Reticular Chemistry: Occurrence and Taxonomy of Nets and Grammar for the Design of Frameworks journal March 2005
PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS patent-application July 2010
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks journal June 2006
Reticular synthesis and the design of new materials journal June 2003
A metal–organic framework material that functions as an enantioselective catalyst for olefin epoxidation journal January 2006
Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials journal September 2008
From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites journal March 1999
Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake journal August 2011
Improved Designs of Metal-Organic Frameworks for Hydrogen Storage journal July 2007
Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature journal December 2005
Covalently linked organic frameworks and polyhedra patent September 2009
Process for preparing hydrogen peroxide from the elements patent-application March 2006
Construction of a new open-framework solid from 1,3,5-cyclohexanetricarboxylate and zinc(II) building blocks
  • Yaghi, Omar M.; Jernigan, Ryan; Li, Hailian
  • Journal of the Chemical Society, Dalton Transactions, Vol. 0, Issue 14, p. 2383-2384 https://doi.org/10.1039/a702287e
journal January 1997
Design, Synthesis, Structure, and Gas (N2, Ar, CO2, CH4, and H2) Sorption Properties of Porous Metal-Organic Tetrahedral and Heterocuboidal Polyhedra
  • Sudik, Andrea C.; Millward, Andrew R.; Ockwig, Nathan W.
  • Journal of the American Chemical Society, Vol. 127, Issue 19, p. 7110-7118 https://doi.org/10.1021/ja042802q
journal May 2005
Non-carboxylate based metal-organic frameworks (MOFs) and related aspects journal June 2009
Gas storage system patent-application December 2004
Thermal conductivity of a metal-organic framework (MOF-5): Part II. Measurement journal February 2007
PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS patent-application August 2007
High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture journal February 2008
Synthesis of Metal−Organic Complex Arrays
  • Vairaprakash, Pothiappan; Ueki, Hisanori; Tashiro, Kentaro
  • Journal of the American Chemical Society, Vol. 133, Issue 4, p. 759-761 https://doi.org/10.1021/ja1097644
journal February 2011
Crystals as Molecules Postsynthesis Covalent Functionalization of Zeolitic Imidazolate Frameworks
  • Morris, William; Doonan, Christian J.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 130, Issue 38, p. 12626-12627 https://doi.org/10.1021/ja805222x
journal September 2008
Noninterpenetrating Indium Sulfide Supertetrahedral Cristobalite Framework journal June 1999
Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications journal July 2009
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent August 2005
Effects of Functionalization, Catenation, and Variation of the Metal Oxide and Organic Linking Units on the Low-Pressure Hydrogen Adsorption Properties of Metal−Organic Frameworks journal February 2006
Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach journal June 2008
A route to high surface area, porosity and inclusion of large molecules in crystals journal February 2004
The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets journal December 2008
A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of Alkanes journal February 2006
ADSORPTIVE GAS SEPARATION OF MULTI-COMPONENT GASES patent-application June 2010
Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
  • Mendoza-Cortés, José L.; Han, Sang Soo; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry A, Vol. 114, Issue 40, p. 10824-10833 https://doi.org/10.1021/jp1044139
journal October 2010
High-Throughput Synthesis of Phosphonate-Based Inorganic–Organic Hybrid Compounds under Hydrothermal Conditions journal January 2004
Metal-organic framework materials for gaseous hydrocarbon storage patent-application August 2006
20 Å Cd4In16S3514- Supertetrahedral T4 Clusters as Building Units in Decorated Cristobalite Frameworks journal May 2001
Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of CuII(1,4-C4H4N2)(C4O4)(OH2)4 journal July 1995
Construction of Microporous Materials from Molecular Building Blocks book January 2002
Characterization of H2 Binding Sites in Prototypical Metal−Organic Frameworks by Inelastic Neutron Scattering
  • Rowsell, Jesse L. C.; Eckert, Juergen; Yaghi, Omar M.
  • Journal of the American Chemical Society, Vol. 127, Issue 42, p. 14904-14910 https://doi.org/10.1021/ja0542690
journal October 2005
A Flexible Germanate Structure Containing 24-Ring Channels and with Very Low Framework Density journal December 2001
Metal-organic frameworks with high capacity and selectivity for harmful gases journal August 2008
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application April 2003
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent-application June 2006
Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework journal October 2007
Cu2(ATC)·6H2O:  Design of Open Metal Sites in Porous Metal−Organic Crystals (ATC:  1,3,5,7-Adamantane Tetracarboxylate) journal November 2000
Gas Adsorption Sites in a Large-Pore Metal-Organic Framework journal August 2005
Porous organo-metallic skeleton material containing an additional polymer patent October 2010
Understanding Inflections and Steps in Carbon Dioxide Adsorption Isotherms in Metal-Organic Frameworks journal January 2008
Ge2ZrO6F2·(H2DAB)H2O:1  A 4-Connected Microporous Material with “Bow Tie” Building Units and an Exceptional Proportion of 3-Rings journal December 2000
Three-periodic nets and tilings: semiregular nets journal October 2003
Metal–organic frameworks: a new class of porous materials journal August 2004
Method of storing, uptaking, releasing of gases by novel framework materials patent-application August 2003
Metal-organic polyhedra patent-application June 2005
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites journal November 2009
Robust dynamics journal May 2010
Process for preparing hydrogen peroxide from the elements patent-application April 2004
Zeolite-like metal organic frameworks (ZMOFS): modular approach to the synthesis of organic-inorganic hybrid porous materials having a zeolite like topology patent-application December 2006
Non-regenerating carbon monoxide sensor patent March 1998
A Metal−Organic Framework with Covalently Bound Organometallic Complexes journal July 2010
Gas storage system patent December 2007
MOF-74 building unit has a direct impact on toxic gas adsorption journal January 2011
Hydrogen-Bonded Complexes of Aromatic Crown Ethers with (9-Anthracenyl)methylammonium Derivatives. Supramolecular Photochemistry and Photophysics. pH-Controllable Supramolecular Switching
  • Ashton, Peter R.; Ballardini, Roberto; Balzani, Vincenzo
  • Journal of the American Chemical Society, Vol. 119, Issue 44, p. 10641-10651 https://doi.org/10.1021/ja9715760
journal November 1997
NMR Studies on the Diffusion of Hydrocarbons on the Metal-Organic Framework Material MOF-5 journal March 2006
Heterogeneity within Order in Crystals of a Porous Metal–Organic Framework journal August 2011
Frameworks for Extended Solids: Geometrical Design Principles journal June 2000
Metal–organic frameworks with designed chiral recognition sites journal January 2010
Process for producing polyalkylene carbonates patent September 2003
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks journal February 2010
Positronium formation in porous materials for antihydrogen production journal April 2010
Shaped bodies containing metal-organic frameworks patent April 2009
Synthesis and Characterization of Zirconogermanates journal September 2003
CRYSTALLINE 3D- AND 2D COVALENT ORGANIC FRAMEWORKS patent-application June 2010
Mutually Interpenetrating Sheets and Channels in the Extended Structure of [Cu(4,4′-bpy)Cl] journal February 1995
Crystalline metal-organic microporous materials patent July 1997
Rotaxanes as ligands: from molecules to materials journal January 2007
A Molecular Railroad with Large Pores:  Synthesis and Structure of Ni(4,4‘-bpy)2.5(H2O)2(ClO4)2·1.5(4,4‘-bpy)·2H2O journal September 1997
Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirs journal May 2008
A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials journal November 2005
Large Free Volume in Maximally Interpenetrating Networks:  The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO]1 journal May 2000
Design of Solids from Molecular Building Blocks: Golden Opportunities for Solid State Chemistry journal June 2000
EDIBLE AND BIOCOMPATIBLE METAL-ORGANIC FRAMEWORKS patent-application November 2010
Dramatic Tuning of Carbon Dioxide Uptake via Metal Substitution in a Coordination Polymer with Cylindrical Pores
  • Caskey, Stephen R.; Wong-Foy, Antek G.; Matzger, Adam J.
  • Journal of the American Chemical Society, Vol. 130, Issue 33, p. 10870-10871 https://doi.org/10.1021/ja8036096
journal August 2008
A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst journal August 2002
Designed Synthesis of 3D Covalent Organic Frameworks journal April 2007
Crystalline membranes patent-application January 2005
Late transition metal catalyst complexes and oligomers therefrom patent December 2002
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent October 2007
Taxonomy of periodic nets and the design of materials journal January 2007
High gas adsorption metal-organic framework patent February 2010
Highly Porous and Stable Metal−Organic Frameworks: Structure Design and Sorption Properties journal February 2000
SHAPED BODIES CONTAINING METAL-ORGANIC FRAMEWORKS patent-application June 2009
Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature patent-application March 2007
Porous Metal−Organic Truncated Octahedron Constructed from Paddle-Wheel Squares and Terthiophene Links journal September 2005
Process for the epoxidation of an organic compound with oxygen or an oxygen-delivering compounds using catalysts containing metal-organic frame-work materials patent September 2003

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