Weak-link capacitor
A process for making a dielectric material where a precursor polymer selected from poly(phenylene vinylene)polyacetylene, poly(p-phenylene), poly(thienylene vinylene), poly(1,4-naphthylene vinylene), and poly(p-pyridine vinylene) is energized said by exposure by radiation or increase in temperature to a level sufficient to eliminate said leaving groups contained within the precursor polymer, thereby transforming the dielectric material into a conductive polymer. The leaving group in the precursor polymer can be a chloride, a bromide, an iodide, a fluoride, an ester, an xanthate, a nitrile, an amine, a nitro group, a carbonate, a dithiocarbamate, a sulfonium group, an oxonium group, an iodonium group, a pyridinium group, an ammonium group, a borate group, a borane group, a sulphinyl group, or a sulfonyl group.
- Research Organization:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC04-94AL85000
- Assignee:
- Sandia Corporation (Albuquerqoe, NM)
- Patent Number(s):
- 8,426,321
- Application Number:
- 13/099,143
- OSTI ID:
- 1083597
- Country of Publication:
- United States
- Language:
- English
Soluble precursor to poly (cyanoterephthalydene) and method of preparation
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patent | December 1995 |
S-benzoyl O-ethyl xanthate as a new photoinitiator: Photopolymerization and laser flash photolysis studies
|
journal | March 1993 |
Thermally Induced Failure of Polymer Dielectrics
|
journal | April 2010 |
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