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Title: Thermally switchable dielectrics

Patent ·
OSTI ID:1083586

Precursor polymers to conjugated polymers, such as poly(phenylene vinylene), poly(poly(thiophene vinylene), poly(aniline vinylene), and poly(pyrrole vinylene), can be used as thermally switchable capacitor dielectrics that fail at a specific temperature due to the non-conjugated precursor polymer irreversibly switching from an insulator to the conjugated polymer, which serves as a bleed resistor. The precursor polymer is a good dielectric until it reaches a specific temperature determined by the stability of the leaving groups. Conjugation of the polymer backbone at high temperature effectively disables the capacitor, providing a `built-in` safety mechanism for electronic devices.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
Assignee:
Sandia Corporation (Albuquerque, NM)
Patent Number(s):
8,427,809
Application Number:
13/034,535
OSTI ID:
1083586
Country of Publication:
United States
Language:
English

References (19)

A New Family of Highly Emissive Soluble Poly( p -phenylene vinylene) Derivatives. A Step toward Fully Conjugated Blue-Emitting Poly( p -phenylene vinylenes) journal January 1998
Synthesis and properties of new polyimides containing flourinated alkoxy side chains journal January 1990
General observation of n-type field-effect behaviour in organic semiconductors journal March 2005
AB initio MRD CI potential curves, dipole moments and zero-field splittings for the X2Π ground states of the CF and CCl molecules journal January 1986
Doping and conductivity studies on poly(p-phenylene vinylene) journal July 1997
Effect of lithium doping on the conductivity of poly(p-phenylene vinylene) journal April 1994
Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices journal March 2009
Synthesis of Conjugated Polymers for Organic Solar Cell Applications journal November 2009
Synthesis and electrical conductivities of poly(2,3,5,6-tetramethoxy-1,4-phenylenevinylene) and a series of poly(1,4-phenylenevinylene-co-2,3,5,6-tetramethoxy-1,4-phenylenevinylenes) journal April 1993
Chlorine precursor route (CPR) chemistry to poly(p-phenylene vinylene)-based light emitting diodes journal January 1995
Polyphenylene-Based Materials for Organic Photovoltaics journal November 2010
Polarization Effects of Fluorine on the Relative Permittivity in Polyimides journal October 1994
Preparation and properties of highly conducting poly(arylene vinylenes) journal April 1991
Halogen Precursor Route to Poly[(2,3-diphenyl- p -phenylene)vinylene] (DP-PPV):  Synthesis, Photoluminescence, Electroluminescence, and Photoconductivity journal October 1997
Anagostic Interactions and Catalytic Activities of Sterically Bulky Benzannulated N-Heterocyclic Carbene Complexes of Nickel(II) journal April 2008
Soluble precursor to poly (cyanoterephthalydene) and method of preparation patent December 1995
Synthesis of Highly Phenylated Poly( p -phenylenevinylenes) via a Chlorine Precursor Route journal January 1998
Electroluminescence in conjugated polymers journal January 1999
Synthesis and Properties of Highly Fluorinated Polyimides journal June 1994

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