Refractory Materials based on Magnesia-Alumina Spinel for Improved Performance in Coal Gasification Environments

Conference · Tue Jan 01 04:00:00 EST 2013

OSTI ID:1072151

Hemrick, James Gordon ^[1]; Armstrong, Beth L ^[1]; Rodrigues-Schroer, Angela ^[2]; Colavito, ^[2]; Smith, Jeffrey D ^[1]; O'Hara, Kelley ^[3]

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1. ORNL
2. Minteq International, Inc.
3. University of Missouri, Rolla

As part of a larger project to develop novel refractory systems and techniques to reduce energy consumption of refractory lined vessels, a team composed of Oak Ridge National Laboratory, refractory manufacturer Minteq International, Inc., and academic partner Missouri University of Science and Technology have developed new refractory materials and coating systems specifically for application in coal gasification environments. Materials were developed under this U.S. DOE funded project to address the need for innovative refractory compositions by developing MgO-Al2O3 spinel gunnable refractory compositions utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques. Work was conducted to develop and deploy these new materials and to develop and apply low cost coatings using a colloidal approach for protection against attack of the refractory brick by the serviced environment. Additionally, a light-weight back-up refractory system was developed to help offset the high thermal conductivity inherent in spinel materials. This paper discusses the efforts involved in the development of these materials, along with the laboratory testing and evaluation of these materials leading to relevant results achieved toward the reduction of chemical reactions and mechanical degradation by the service environment though compositional and processing modifications.

• Research Organization: Oak Ridge National Laboratory (ORNL)
• Sponsoring Organization: EE USDOE - Office of Energy Efficiency and Renewable Energy (EE)
• DOE Contract Number: AC05-00OR22725
• OSTI ID: 1072151
• Country of Publication: United States
• Language: English