Synthesis and structure of ({eta}{sup 5}-C{sub 5}Me{sub 5}){sub 2}Zr(Se)CO, a nonclassical d{sup 0} zirconium carbonyl complex
- Columbia Univ., New York, NY (United States)
Cp*{sub 2}Zr(Se)CO (Cp = {eta}{sup 5}-C{sub 5}Me{sub 5}), an example of a nonclassical d{sup 0} transition-metal carbonyl complex, has been synthesized by the reaction of Cp{sub 2}Zr(CO){sub 2} with elemental Se (ca. 1 equiv) at 50{degree}C. The CO ligand in Cp{sub 2}Zr(Se)CO is labile and is rapidly displaced by pyridine to give Cp{sub 2}Zr(Se)(NC{sub 5}H{sub 5}). 26 refs., 2 figs., 1 tab.
- DOE Contract Number:
- FG02-93ER14339
- OSTI ID:
- 106753
- Journal Information:
- Organometallics, Vol. 14, Issue 9; Other Information: PBD: Sep 1995
- Country of Publication:
- United States
- Language:
- English
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