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Title: Nitrogen composition dependence of electron effective mass in GaAs1-xNx

Journal Article · · Physical Review. B, Condensed Matter and Materials Physics
 [1];  [2];  [2];  [2];  [3];  [2];  [1];  [2];  [2]
  1. Univ. College Cork (Ireland); Univ. of Michigan, Ann Arbor, MI (United States)
  2. Univ. of Michigan, Ann Arbor, MI (United States)
  3. Univ. College Cork (Ireland)

We have investigated the N composition, x , and temperature, T , dependence of the electron effective mass, m*, of GaAs1-x Nx films with sufficiently low carrier concentration that carriers are expected to be confined to near the bottom of the conduction-band edge (CBE). Using Seebeck and Hall measurements, in conjunction with assumptions of parabolic bands and Fermi-Dirac statistics, we find a nonmonotonic dependence of m* on x and an increasing T dependence of m* with x . These trends are not predicted by the two-state band anticrossing model but instead are consistent with the predictions of the linear combination of resonant nitrogen states model, which takes into account several N-related states and their interaction with the GaAs CBE.

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Solar and Thermal Energy Conversion (CSTEC)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0000957
OSTI ID:
1064867
Journal Information:
Physical Review. B, Condensed Matter and Materials Physics, Vol. 82; Related Information: CSTEC partners with University of Michigan (lead); Kent State University; ISSN 1098-0121
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English