Chemical contrast in STM imaging of transition metal aluminides

Journal Article · Wed Aug 01 04:00:00 EDT 2012 · Progress in Surface Science

DOI:https://doi.org/10.1016/j.progsurf.2012.05.002· OSTI ID:1060751

Duguet, T; Thiel, Patricia A

The present manuscript reviews recent scanning tunnelling microscopy (STM) studies of transition metal (TM) aluminide surfaces. It provides a general perspective on the contrast between Al atoms and TM atoms in STM imaging. A general trend is the much stronger bias dependence of TM atoms, or TM-rich regions of the surface. This dependence can be attenuated by the local chemical arrangements and environments. Al atoms can show a stronger bias dependence when their chemical environment, such as their immediate subsurface, is populated with TM. All this is well explained in light of combined results of STM and both theoretical and experimental electronic and crystallographic structure determinations. Since STM probes the Fermi surface, the electronic structure in the vicinity of the Fermi level (EF) is essential for understanding contrast and bias dependence. Hence, partial density of states provides information about the TM d band position and width, s–p–d hybridization or interactions, or charge transfer between constituent elements. In addition, recent developments in STM image simulations are very interesting for elucidating chemical contrast at Al–TM alloy surfaces, and allow direct atomic identification, when the surface does not show too much disorder. Overall, we show that chemically-specific imaging is often possible at these surfaces.

• Research Organization: Ames Laboratory (AMES), Ames, IA (United States)
• Sponsoring Organization: USDOE Office of Science (SC)
• DOE Contract Number: AC02-07CH11358
• OSTI ID: 1060751
• Report Number(s): IS-J 7813
• Journal Information: Progress in Surface Science, Journal Name: Progress in Surface Science Journal Issue: 5-8 Vol. 87; ISSN 0079-6816
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
Scanning tunneling microscopy Chemical contrast Aluminium transition metal alloys Valence band structure