Absolute photoionization cross-sections of some combustion intermediates

Yang, Bin; Wang, Juan; Cool, Terrill A.; Hansen, Nils; Skeen, Scott; Osborn, David L.

doi:10.1016/j.ijms.2011.09.006

Absolute photoionization cross-sections of some combustion intermediates

Journal Article · Sun Jan 01 04:00:00 EST 2012 · International Journal of Mass Spectrometry

DOI:https://doi.org/10.1016/j.ijms.2011.09.006· OSTI ID:1060389

Yang, Bin ^[1]; Wang, Juan; Cool, Terrill A.; Hansen, Nils; Skeen, Scott; Osborn, David L.

Combustion Research Facility, Sandia National Laboratories, Livermore, CA 94551

Near-threshold absolute photoionization and dissociative photoionization cross-sections for photon energies from 9.7 to 11.75 eV are presented for 30 combustion intermediates including hydrocarbons, oxygenates and nitrogenous compounds (trans-2-butene, 2-methyl-1-butene, 3-methyl-1-butene, 2-methyl-2-butene, trans-2-hexene, 1-hexene, allene, 1,3-butadiene, 1,3-pentadiene, 1,4-pentadiene, 3-methyl-1,2-butadiene, 1,5-hexadiene, isobutane, methylcyclohexane, furan, 2,3-dihydrofuran, 2,5-dihydrofuran, 2-methyltetrahydrofuran, tetrahydropyran, n-butanal, isobutanal, 2-butenal, 3-methyl-2-butenal, ketene, allyl alcohol, methyl vinyl ketone, dimethoxymethane, methylamine, ethylamine, piperidine). Because allene is one of the most important intermediates in hydrocarbon combustion and pyrolysis processes, very accurate cross-sections for allene are desired to enable the measurement of its mole fractions in flames and to determine relative concentration ratios of allene to its isomer propyne. The cross-sections for allene have thus been re-measured with high precision using an apparatus of improved signal/noise ratio. Furthermore, these allene cross-sections yield accurate previously unmeasured cross-sections for ketene, another key combustion intermediate.

Research Organization:: Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-01ER15180

OSTI ID:: 1060389

Report Number(s):: DOE-ER15180-1

Journal Information:: International Journal of Mass Spectrometry, Journal Name: International Journal of Mass Spectrometry Journal Issue: 1 Vol. 309; ISSN 1387-3806

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Combustion chemistry
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Absolute photoionization cross-sections of some combustion intermediates

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