Lithium-sulfur batteries based on nitrogen-doped carbon and ionic liquid electrolyte

Journal Article · Sat Dec 31 23:00:00 EST 2011 · ChemSuSChem

DOI:https://doi.org/10.1002/cssc.201200101· OSTI ID:1055042

Sun, Xiao-Guang ^[1]; Wang, Xiqing ^[1]; Mayes, Richard T ^[1]; Dai, Sheng ^[1]

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1. ORNL

Nitrogen-doped mesoporous carbon (NC) and sulfur were used to prepare an NC/S composite cathode, which was evaluated in an ionic liquid electrolyte of 0.5 M lithium bis(trifluoromethane sulfonyl)imide (LiTFSI) in methylpropylpyrrolidinium bis(trifluoromethane sulfonyl)imide (MPPY.TFSI) by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and cycle testing. To facilitate the comparison, a C/S composite based on activated carbon (AC) without nitrogen doping was also fabricated under the same conditions as those for the NC/S composite. Compared with the AC/S composite, the NC/S composite showed enhanced activity toward sulfur reduction, as evidenced by the early onset sulfur reduction potential, higher redox current density in the CV test, and faster charge transfer kinetics as indicated by EIS measurement. At room temperature under a current density of 84 mA g-1 (C/20), the battery based on the NC/S composite exhibited higher discharge potential and an initial capacity of 1420 mAh g-1 whereas that based on the AC/S composite showed lower discharge potential and an initial capacity of 1120 mAh g-1. Both batteries showed similar capacity fading with cycling due to the intrinsic polysulfide solubility and the polysulfide shuttle mechanism; the capacity fading can be improved by further modification of the cathode.

• Research Organization: Oak Ridge National Laboratory (ORNL)
• Sponsoring Organization: SC USDOE - Office of Science (SC)
• DOE Contract Number: AC05-00OR22725
• OSTI ID: 1055042
• Journal Information: ChemSuSChem, Journal Name: ChemSuSChem Journal Issue: 10 Vol. 5; ISSN 1864-5631
• Country of Publication: United States
• Language: English