Visible light responsive iodine-doped TiO2 for photocatalytic reduction of CO2 to fuels

Zhang, Qianyi; Li, Ying; Ackerman, Erik A.; Gajdardziska-Josifovska, Marija; Li, Hailong

doi:10.1016/j.apcata.2011.04.032

Visible light responsive iodine-doped TiO₂ for photocatalytic reduction of CO₂ to fuels

Journal Article · Wed Jun 01 04:00:00 EDT 2011 · Applied Catalysis. A, General

DOI:https://doi.org/10.1016/j.apcata.2011.04.032· OSTI ID:1051024

Zhang, Qianyi ^[1]; Li, Ying; Ackerman, Erik A.; Gajdardziska-Josifovska, Marija; Li, Hailong

University of Wisconsin-Milwaukee

Iodine-doped titanium oxide (I-TiO₂) nanoparticles that are photocatalitically responsive to visible light illumination have been synthesized by hydrothermal method. The structure and properties of I-TiO₂ nanocrystals prepared with different iodine doping levels and/or calcination temperatures were characterized by X-ray diffraction, transmission electron microscopy and diffraction, X-ray photoelectron spectroscopy, and UV-vis diffuse reflectance spectra. The three nominal iodine dopant levels (5, 10, 15 wt.%) and the two lower calcination temperatures (375, 450°C) produced mixture of anatase and brookite nanocrystals, with small fraction of rutile found at 550°C. The anatase phase of TiO₂ increased in volume fraction with increased calcination temperature and iodine levels. The photocatalytic activities of the I-TiO₂ powders were investigated by photocatalytic reduction of CO₂ with H₂O under visible light (λ > 400 nm) and also under UV-vis illumination. CO was found to be the major photoreduction product using both undoped and doped TiO₂. A high CO₂ reduction activity was observed for I-TiO² catalysts (highest CO yield equivalent to 2.4 micro mol g^-1 h^-1) under visible light, and they also had much higher CO₂ photoreduction efficiency than undoped TiO₂ under UV-vis irradiation. I-TiO₂ calcined at 375°C has superior activity to those calcined at higher temperatures. Optimal doping levels of iodine were identified under visible and UV-vis irradiations, respectively. This is the first study that investigates nonmetal doped TiO² without other co-catalysts for CO₂ photoreduction to fuels under visible light.

Research Organization:: Univ. of Wisconsin, Milwaukee, WI (United States)

Sponsoring Organization:: USDOE SC Office of Basic Energy Sciences (SC-22)

DOE Contract Number:: FG02-06ER46328

OSTI ID:: 1051024

Report Number(s):: DOE/ER/46328-5

Journal Information:: Applied Catalysis. A, General, Journal Name: Applied Catalysis. A, General Journal Issue: 1-2 Vol. 400; ISSN 0926-860X

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

References (46)

Dye sensitized CO2 reduction over pure and platinized TiO2 Ozcan, O.; Yukruk, F.; Akkaya, E. U. Topics in Catalysis, Vol. 44, Issue 4 https://doi.org/10.1007/s11244-006-0100-z	journal	July 2007
A facile approach to synthesize N and B co-doped TiO2 nanomaterials with superior visible-light response Wu, Guosheng; Wen, Jiali; Wang, Jingpeng Materials Letters, Vol. 64, Issue 15 https://doi.org/10.1016/j.matlet.2010.04.024	journal	August 2010
High-Rate Solar Photocatalytic Conversion of CO ₂ and Water Vapor to Hydrocarbon Fuels Varghese, Oomman K.; Paulose, Maggie; LaTempa, Thomas J. Nano Letters, Vol. 9, Issue 2 https://doi.org/10.1021/nl803258p	journal	February 2009
Enhanced TiO2 photocatalysis by Cu in hydrogen production from aqueous methanol solution Wu, N. International Journal of Hydrogen Energy, Vol. 29, Issue 15 https://doi.org/10.1016/j.ijhydene.2004.02.013	journal	December 2004
Photocatalytic reduction of CO2 with H2O on TiO2 and Cu/TiO2 catalysts Yamashita, H.; Nishiguchi, H.; Kamada, N. Research on Chemical Intermediates, Vol. 20, Issue 8 https://doi.org/10.1163/156856794X00568	journal	January 1994
Photocatalytic reduction of CO₂ with H₂O on mesoporous silica supported Cu/TiO₂ catalysts Li, Ying; Wang, Wei-Ning; Zhan, Zili Applied Catalysis B: Environmental, Vol. 100, Issue 1-2, p. 386-392 https://doi.org/10.1016/j.apcatb.2010.08.015	journal	October 2010
Photoreduction of carbon dioxide with H2 and H2O over TiO2 and ZrO2 in a circulated photocatalytic reactor Lo, Cho-Ching; Hung, Chung-Hsuang; Yuan, Chung-Shin Solar Energy Materials and Solar Cells, Vol. 91, Issue 19 https://doi.org/10.1016/j.solmat.2007.06.003	journal	November 2007
Iodine-Doped TiO₂ Photocatalysts: Correlation between Band Structure and Mechanism Tojo, Sachiko; Tachikawa, Takashi; Fujitsuka, Mamoru The Journal of Physical Chemistry C, Vol. 112, Issue 38 https://doi.org/10.1021/jp804985f	journal	August 2008
Structural and electronic properties of iodine-doped anatase and rutile TiO2 Long, Run; Dai, Ying; Huang, Baibiao Computational Materials Science, Vol. 45, Issue 2 https://doi.org/10.1016/j.commatsci.2008.09.011	journal	April 2009
Electron paramagnetic resonance study of transition-metal-ion impregnated brookite titanium dioxide powders Amorelli, Angelo; Evans, Jeffrey C.; Rowlands, Christopher C. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 85, Issue 12 https://doi.org/10.1039/f19898504031	journal	January 1989
Photocatalytic Reduction of CO ₂ to CO in the Presence of H ₂ or CH ₄ as a Reductant over MgO Teramura, Kentaro; Tanaka, Tsunehiro; Ishikawa, Haruka The Journal of Physical Chemistry B, Vol. 108, Issue 1 https://doi.org/10.1021/jp0362943	journal	January 2004
Separation and Capture of CO ₂ from Large Stationary Sources and Sequestration in Geological Formations—Coalbeds and Deep Saline Aquifers White, Curt M.; Strazisar, Brian R.; Granite, Evan J. Journal of the Air & Waste Management Association, Vol. 53, Issue 6 https://doi.org/10.1080/10473289.2003.10466206	journal	June 2003
Photocatalytic Activity of S-doped TiO ₂ Photocatalyst under Visible Light Ohno, Teruhisa; Mitsui, Takahiro; Matsumura, Michio Chemistry Letters, Vol. 32, Issue 4 https://doi.org/10.1246/cl.2003.364	journal	April 2003
Effects of I and F codoped TiO2 on the photocatalytic degradation of methylene blue Wen, Chen; Zhu, Yu-Jie; Kanbara, Takaki Desalination, Vol. 249, Issue 2 https://doi.org/10.1016/j.desal.2009.01.028	journal	December 2009
Efficient Photochemical Water Splitting by a Chemically Modified n-TiO2 Khan, S. U. M. Science, Vol. 297, Issue 5590 https://doi.org/10.1126/science.1075035	journal	September 2002
Photocatalytic performance of Ru doped anatase mounted on silica for reduction of carbon dioxide Sasirekha, N.; Basha, S.; Shanthi, K. Applied Catalysis B: Environmental, Vol. 62, Issue 1-2 https://doi.org/10.1016/j.apcatb.2005.07.009	journal	January 2006
Effect of H2 gas as a reductant on photoreduction of CO2 over a Ga2O3 photocatalyst Teramura, Kentaro; Tsuneoka, Hideo; Shishido, Tetsuya Chemical Physics Letters, Vol. 467, Issue 1-3 https://doi.org/10.1016/j.cplett.2008.10.079	journal	December 2008
CO2 photoreduction using NiO/InTaO4 in optical-fiber reactor for renewable energy Wang, Zhen-Yi; Chou, Hung-Chi; Wu, Jeffrey C. S. Applied Catalysis A: General, Vol. 380, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.03.059	journal	May 2010
Photocatalytic carbon dioxide photoreduction by Co(bpy)32+ sensitized by Ru(bpy)32+ fixed to cation exchange polymer Hirose, Takuji; Maeno, Yoshihito; Himeda, Yuichiro Journal of Molecular Catalysis A: Chemical, Vol. 193, Issue 1-2, p. 27-32 https://doi.org/10.1016/S1381-1169(02)00478-8	journal	February 2003
Visible light-activated N-F-codoped TiO2 nanoparticles for the photocatalytic degradation of microcystin-LR in water Pelaez, Miguel; de la Cruz, Armah A.; Stathatos, Elias Catalysis Today, Vol. 144, Issue 1-2 https://doi.org/10.1016/j.cattod.2008.12.022	journal	June 2009
Preparation and characterization of N–I co-doped nanocrystal anatase TiO2 with enhanced photocatalytic activity under visible-light irradiation Zhou, Liang; Deng, Jian; Zhao, Yubao Materials Chemistry and Physics, Vol. 117, Issue 2-3 https://doi.org/10.1016/j.matchemphys.2009.06.036	journal	October 2009
Preparation and characterization of S-doped TiO2 nanoparticles, effect of calcination temperature and evaluation of photocatalytic activity Hamadanian, M.; Reisi-Vanani, A.; Majedi, A. Materials Chemistry and Physics, Vol. 116, Issue 2-3 https://doi.org/10.1016/j.matchemphys.2009.03.039	journal	August 2009
Effect of silver doping on the TiO2 for photocatalytic reduction of CO2 Kočí, K.; Matějů, K.; Obalová, L. Applied Catalysis B: Environmental, Vol. 96, Issue 3-4 https://doi.org/10.1016/j.apcatb.2010.02.030	journal	June 2010
Influence of hydroxyl contents on photocatalytic activities of polymorphic titania nanoparticles Kaewgun, Sujaree; Nolph, Christopher A.; Lee, Burtrand I. Materials Chemistry and Physics, Vol. 114, Issue 1 https://doi.org/10.1016/j.matchemphys.2008.09.072	journal	March 2009
Multivalency Iodine Doped TiO₂: Preparation, Characterization, Theoretical Studies, and Visible-Light Photocatalysis Su, Wenyue; Zhang, Yongfan; Li, Zhaohui Langmuir, Vol. 24, Issue 7 https://doi.org/10.1021/la701645y	journal	February 2008
Photocatalytic reduction of CO₂ with H₂O on various titanium oxide catalysts Anpo, Masakazu; Yamashita, Hiromi; Ichihashi, Yuichi Journal of Electroanalytical Chemistry, Vol. 396, Issue 1-2, p. 21-26 https://doi.org/10.1016/0022-0728(95)04141-A	journal	October 1995
Size effect on phase transition sequence of TiO2 nanocrystal Zhu, Ke-Rong; Zhang, Ming-Sheng; Hong, Jian-Ming Materials Science and Engineering: A, Vol. 403, Issue 1-2 https://doi.org/10.1016/j.msea.2005.04.029	journal	August 2005
Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides Asahi, R. Science, Vol. 293, Issue 5528 https://doi.org/10.1126/science.1061051	journal	July 2001
Visible-Light-Activated Nanoparticle Photocatalyst of Iodine-Doped Titanium Dioxide Hong, Xiaoting; Wang, Zhengpeng; Cai, Weimin Chemistry of Materials, Vol. 17, Issue 6 https://doi.org/10.1021/cm047891k	journal	February 2005
Photocatalytic reduction of CO2 over TiO2 based catalysts Kočí, Kamila; Obalová, Lucie; Lacný, Zdeněk Chemical Papers, Vol. 62, Issue 1 https://doi.org/10.2478/s11696-007-0072-x	journal	January 2008
Size dependence of thermal stability of TiO2 nanoparticles Li, W.; Ni, C.; Lin, H. Journal of Applied Physics, Vol. 96, Issue 11 https://doi.org/10.1063/1.1807520	journal	December 2004
Effects of F ^- Doping on the Photocatalytic Activity and Microstructures of Nanocrystalline TiO ₂ Powders Yu, Jimmy C. Chemistry of Materials, Vol. 14, Issue 9 https://doi.org/10.1021/cm020027c	journal	September 2002
Photocatalytic Activity of (Copper, Nitrogen)‐Codoped Titanium Dioxide Nanoparticles Song, Kaixi; Zhou, Jiahong; Bao, Jianchun Journal of the American Ceramic Society, Vol. 91, Issue 4 https://doi.org/10.1111/j.1551-2916.2008.02291.x	journal	April 2008
EXAFS study and photocatalytic properties of un-doped and iron-doped ZrO2-TiO2 (photo-) catalysts Hidalgo, M.; Colon, G.; Navio, J. Catalysis Today, Vol. 128, Issue 3-4 https://doi.org/10.1016/j.cattod.2007.07.010	journal	October 2007
Iodine doped anatase TiO2 photocatalyst with ultra-long visible light response: correlation between geometric/electronic structures and mechanisms Liu, Gang; Sun, Chenghua; Yan, Xiaoxia Journal of Materials Chemistry, Vol. 19, Issue 18 https://doi.org/10.1039/b820816f	journal	January 2009
Transformation of brookite-type TiO2 nanocrystals to rutile: correlation between microstructure and photoactivity Bakardjieva, Snejana; Stengl, Vaclav; Szatmary, Lorant Journal of Materials Chemistry, Vol. 16, Issue 18 https://doi.org/10.1039/b514632a	journal	January 2006
Doping ofTiO2Polymorphs for Altered Optical and Photocatalytic Properties Nie, Xiliang; Zhuo, Shuping; Maeng, Gloria International Journal of Photoenergy, Vol. 2009 https://doi.org/10.1155/2009/294042	journal	January 2009
Enhanced photocatalytic activity of TiO2 by doping with Ag for degradation of 2,4,6-trichlorophenol in aqueous suspension Rengaraj, S.; Li, X. Z. Journal of Molecular Catalysis A: Chemical, Vol. 243, Issue 1 https://doi.org/10.1016/j.molcata.2005.08.010	journal	January 2006
Effect of TiO₂ particle size on the photocatalytic reduction of CO₂ Kočí, K.; Obalová, L.; Matějová, L. Applied Catalysis B: Environmental, Vol. 89, Issue 3-4, p. 494-502 https://doi.org/10.1016/j.apcatb.2009.01.010	journal	July 2009
Photoreduction of CO2 using sol–gel derived titania and titania-supported copper catalysts Tseng, I-Hsiang; Chang, Wan-Chen; Wu, Jeffrey C. S. Applied Catalysis B: Environmental, Vol. 37, Issue 1 https://doi.org/10.1016/S0926-3373(01)00322-8	journal	April 2002
Understanding Polymorphic Phase Transformation Behavior during Growth of Nanocrystalline Aggregates: Insights from TiO ₂ Zhang, Hengzhong; Banfield, Jillian F. The Journal of Physical Chemistry B, Vol. 104, Issue 15 https://doi.org/10.1021/jp000499j	journal	April 2000
Photo reduction of CO2 to methanol using optical-fiber photoreactor Wu, Jeffrey C. S.; Lin, Hung-Ming; Lai, Chao-Ling Applied Catalysis A: General, Vol. 296, Issue 2 https://doi.org/10.1016/j.apcata.2005.08.021	journal	December 2005
Effective Visible Light-Activated B-Doped and B,N-Codoped TiO ₂ Photocatalysts In, Suil; Orlov, Alexander; Berg, Regina Journal of the American Chemical Society, Vol. 129, Issue 45 https://doi.org/10.1021/ja0749237	journal	November 2007
Hydrogen production by photocatalytic water-splitting using Cr- or Fe-doped TiO2 composite thin films photocatalyst Dholam, R.; Patel, N.; Adami, M. International Journal of Hydrogen Energy, Vol. 34, Issue 13 https://doi.org/10.1016/j.ijhydene.2009.05.011	journal	July 2009
A Visible Light-Driven Titanium Dioxide Photocatalyst Codoped with Lanthanum and Iodine: An Application in the Degradation of Oxalic Acid He, Zhiqiao; Xu, Xing; Song, Shuang The Journal of Physical Chemistry C, Vol. 112, Issue 42 https://doi.org/10.1021/jp803291c	journal	September 2008
Photocatalytic reduction of CO2 with H2O on Ti-MCM-41 and Ti-MCM-48 mesoporous zeolite catalysts Anpo, Masakazu; Yamashita, Hiromi; Ikeue, Keita Catalysis Today, Vol. 44, Issue 1-4 https://doi.org/10.1016/S0920-5861(98)00206-5	journal	September 1998

Similar Records

A facile method to prepare mesoporous anatase TiO{sub 2} materials in water at lower temperatures

Journal Article · Wed Jul 15 00:00:00 EDT 2015 · Materials Research Bulletin · OSTI ID:22475819

Preparation and characterization of mesoporous N-doped and sulfuric acid treated anatase TiO{sub 2} catalysts and their photocatalytic activity under UV and Vis illumination

Journal Article · Sat Nov 14 23:00:00 EST 2009 · Journal of Solid State Chemistry · OSTI ID:21372389

A novel single-step synthesis of N-doped TiO{sub 2} via a sonochemical method

Journal Article · Mon Nov 14 23:00:00 EST 2011 · Materials Research Bulletin · OSTI ID:22210128

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
CO2 reduction
Nanocomposite
Photocatalysis
Solar energy conversion
TiO2

Visible light responsive iodine-doped TiO2 for photocatalytic reduction of CO2 to fuels

Citation Formats

References (46)

Similar Records

Related Subjects

Visible light responsive iodine-doped TiO₂ for photocatalytic reduction of CO₂ to fuels