Comparative Study of the Defect Point Physics and Luminescence of the Kesterites Cu2ZnSnS4 and Cu2ZnSnSe4 and Chalcopyrite Cu(In,Ga)Se2: Preprint
Conference
·
OSTI ID:1050099
In this contribution, we present a comparative study of the luminescence of the kesterites Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) and their related chalcopyrite Cu(In,Ga)Se2 (CIGSe). Luminescence spectroscopy suggests that the electronic properties of Zn-rich, Cu-poor kesterites (both CZTS and CZTSe) and Cu-poor CIGSe are dictated by fluctuations of the electrostatic and chemical potentials. Thelarge redshift in the luminescence of grain boundaries in CIGSe, associated with the formation of a neutral barrier is clearly observed in CZTSe, and, to some extent, in CZTS. Kesterites can therefore replicate the fundamental electronic properties of CIGSe.
- Research Organization:
- National Renewable Energy Laboratory (NREL), Golden, CO (United States)
- Sponsoring Organization:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Solar Energy Technologies Office (EE-4S)
- DOE Contract Number:
- AC36-08GO28308
- OSTI ID:
- 1050099
- Report Number(s):
- NREL/CP-5200-54140
- Country of Publication:
- United States
- Language:
- English
Similar Records
Nanoscale Measurements of the Surface Photovoltage in Cu(In,Ga)Se2, Cu2ZnSn4, and Cu2ZnSnSe4 Thin Films: The Role of the Surface Electronics on the Efficiency of Solar Cells: Preprint
Kesterites and Chalcopyrites: A Comparison of Close Cousins; Preprint
Nanoscale Measurements of the Surface Photovoltage in Cu(In,Ga)Se2, Cu2ZnSnS4, and Cu2ZnSnSe4 Thin Films: The Role of the Surface Electronics on the Efficiency of Solar Cells
Conference
·
Fri Jul 01 00:00:00 EDT 2011
·
OSTI ID:1021811
Kesterites and Chalcopyrites: A Comparison of Close Cousins; Preprint
Conference
·
Sun May 01 00:00:00 EDT 2011
·
OSTI ID:1015886
Nanoscale Measurements of the Surface Photovoltage in Cu(In,Ga)Se2, Cu2ZnSnS4, and Cu2ZnSnSe4 Thin Films: The Role of the Surface Electronics on the Efficiency of Solar Cells
Conference
·
Fri Dec 31 23:00:00 EST 2010
·
OSTI ID:1049623