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Title: Thermoelectric properties of polycrystalline In4Se3 and In4Te3

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.3389494· OSTI ID:1049924
 [1];  [2];  [2];  [3];  [4]
  1. Optimal Inc., Plymouth, Michigan 48170, USA
  2. GM R&D and Planning, Warren, Michigan
  3. General Motors Corporation-R&D
  4. Oak Ridge National Laboratory (ORNL)

High thermoelectric performance of a single crystal layered compound In{sub 4}Se{sub 3} was reported recently. We present here an electrical and thermal transport property study over a wide temperature range for polycrystalline samples of In{sub 4}Se{sub 3} and In{sub 4}Te{sub 3}. Our data demonstrate that these materials are lightly doped semiconductors, leading to large thermopower and resistivity. Very low thermal conductivity, below 1 W/m K, is observed. The power factors for In{sub 4}Se{sub 3} and In{sub 4}Te{sub 3} are much smaller when compared with state-of-the-art thermoelectric materials. This combined with the very low thermal conductivity results in the maximum ZT value of less than 0.6 at 700 K for In{sub 4}Se{sub 3}.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
DE-AC05-00OR22725
OSTI ID:
1049924
Journal Information:
Applied Physics Letters, Vol. 96, Issue 16; ISSN 0003-6951
Country of Publication:
United States
Language:
English