Effect of H2O and CO2 on The Oxidation Behavior and Durability at High Temperature of ODS-FeCrAl
- ORNL
- CIRIMAT-ENSIACET, Toulouse, France
Cyclic oxidation testing was conducted on alloy MA956 and two different batches of alloy PM2000 at 1100 and 1200 C in different atmospheres rich in O2, H2O and CO2. Compare to 1h cycle in dry O2, exposure in air + 10 vol.% H2O resulted in an increase of the oxidation rate and a decrease of the time to breakaway for both alloys at 1200 C, and a faster consumption of Al in the MA956 alloy. 1h cyclic testing in 50%CO2/50%H2O+0.75% O2 had less of an impact on the oxidation rate but led to an increased formation of voids for alloy MA956, which had an impact on the alloy creep resistance. At 1100 C, exposure in 50%CO2/50%H2O resulted in significant oxide spallation compared with oxidation in air, but it was not the case when 0.75% O2 was added to the CO2/H2O mixture as a buffer. The control of impurities levels drastically improved the PM2000 oxidation resistance.
- Research Organization:
- Oak Ridge National Laboratory (ORNL)
- Sponsoring Organization:
- FE USDOE - Office of Fossil Energy (FE)
- DOE Contract Number:
- AC05-00OR22725
- OSTI ID:
- 1049827
- Country of Publication:
- United States
- Language:
- English
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