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Graphene Monolayer Rotation on Ni(111) Facilities Bilayer Graphene Growth

Journal Article · · Applied Physics Letters
OSTI ID:1049304
Synthesis of bilayer graphene by chemical vapor deposition is of importance for graphene-based field effect devices. Here, we demonstrate that bilayer graphene preferentially grows by carbon-segregation under graphene sheets that are rotated relative to a Ni(111) substrate. Rotated graphene monolayer films can be synthesized at growth temperatures above 650 C on a Ni(111) thin-film. The segregated second graphene layer is in registry with the Ni(111) substrate and this suppresses further C-segregation, effectively self-limiting graphene formation to two layers.
Research Organization:
Brookhaven National Laboratory (BNL) Center for Functional Nanomaterials
Sponsoring Organization:
USDOE SC OFFICE OF SCIENCE (SC)
DOE Contract Number:
AC02-98CH10886
OSTI ID:
1049304
Report Number(s):
BNL--98428-2012-JA; KC020401H
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 24 Vol. 100; ISSN APPLAB; ISSN 0003-6951
Country of Publication:
United States
Language:
English

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