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Title: High-pressure structural phase transitions in chromium-doped BaFe[subscript 2]As[subscript 2]

Journal Article · · J. Phys. Conf. Series

We report on the results from high pressure x-ray powder diffraction and electrical resistance measurements for hole doped BaFe{sub 2-x}Cr{sub x}As{sub 2} (x = 0, 0.05, 0.15, 0.4, 0.61) up to 81 GPa and down to 10 K using a synchrotron source and diamond anvil cell (DAC). At ambient temperature, an isostructural phase transition from a tetragonal (T) phase (I4/mmm) to a collapsed tetragonal (CT) phase is observed at 17 GPa. This transition is found to be dependent on ambient pressure unit cell volume and is slightly shifted to higher pressure upon increase in the Cr-doping. Unlike BaFe{sub 2}As{sub 2} which superconduct under high pressure, we have not detected any evidence of pressure induced superconductivity in chromium doped samples in the pressure and temperature range of this study. The measured equation of state parameters are presented for both the tetragonal and collapsed tetragonal phases for x = 0.05, 0.15, 0.40 and 0.61.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - BASIC ENERGY SCIENCESOTHER U.S. GOVERNMENT
OSTI ID:
1048959
Journal Information:
J. Phys. Conf. Series, Vol. 377, Issue (1) ; 2012; Conference: Mumbai, India
Country of Publication:
United States
Language:
ENGLISH