Quest for highly porous metal-metalloporphyrin framework based upon a custom-designed octatopic porphyrin ligand
- USF
A porous metal-metalloporphyrin framework, MMPF-2, has been constructed from a custom-designed octatopic porphyrin ligand, tetrakis(3,5-dicarboxyphenyl)porphine, that links a distorted cobalt trigonal prism secondary building unit. MMPF-2 possesses permanent microporosity with the highest surface area of 2037 mg2 g-1 among reported porphyrin-based MOFs, and demonstrates a high uptake capcity of 170 cm3 g-1 CO2 at 273 K and 1 bar.
- Research Organization:
- Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)
- Sponsoring Organization:
- UNIVERSITY
- OSTI ID:
- 1046234
- Journal Information:
- Chem. Commun., Journal Name: Chem. Commun. Journal Issue: (57) ; 2012 Vol. 48
- Country of Publication:
- United States
- Language:
- ENGLISH
Similar Records
Three-Dimensional Porous Metal-Metalloporphyrin Framework Consisting of Nanoscopic Polyhedral Cages
Potentiation of radiation-induced cell kill by synthetic metalloporphyrins
Two rare indium-based porous metal-metalloporphyrin frameworks exhibiting interesting CO2 uptake
Journal Article
·
Mon Feb 06 23:00:00 EST 2012
· Journal of the American Chemical Society
·
OSTI ID:1028024
Potentiation of radiation-induced cell kill by synthetic metalloporphyrins
Journal Article
·
Fri Mar 31 23:00:00 EST 1989
· Int. J. Radiat. Oncol., Biol. Phys.; (United States)
·
OSTI ID:6069151
Two rare indium-based porous metal-metalloporphyrin frameworks exhibiting interesting CO2 uptake
Journal Article
·
Sun Jan 12 23:00:00 EST 2014
· CrystEngComm
·
OSTI ID:1110429