Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Ba 1-x Kx Mn2 As2 : An Antiferromagnetic Local-Moment Metal

Journal Article · · Physical Review Letters

The compound BaMn{sub 2}As{sub 2} with the tetragonal ThCr{sub 2}Si{sub 2} structure is a local-moment antiferromagnetic insulator with a Néel temperature T{sub N}=625K and a large ordered moment μ=3.9μ{sub B}/Mn. We demonstrate that this compound can be driven metallic by partial substitution of Ba by K while retaining the same crystal and antiferromagnetic structures together with nearly the same high T{sub N} and large μ. Ba{sub 1-x}K{sub x}Mn{sub 2}As{sub 2} is thus the first metallic ThCr{sub 2}Si{sub 2}-type MAs-based system containing local 3d transition metal M magnetic moments, with consequences for the ongoing debate about the local-moment versus itinerant pictures of the FeAs-based superconductors and parent compounds. The Ba{sub 1-x}K{sub x}Mn{sub 2}As{sub 2} class of compounds also forms a bridge between the layered iron pnictides and cuprates and may be useful to test theories of high T{sub c} superconductivity.

Research Organization:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-07CH11358
OSTI ID:
1044633
Report Number(s):
IS-J--7658
Journal Information:
Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 8 Vol. 108; ISSN 0031-9007
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English

Similar Records

Effects of Co substitution on the structural and magnetic properties of Sr(Ni1-xCox)2P2
Journal Article · Wed Nov 08 23:00:00 EST 2023 · Physical Review. B · OSTI ID:2222449

Crystals, magnetic and electronic properties of a new ThCr{sub 2}Si{sub 2}-type BaMn{sub 2}Bi{sub 2} and K-doped compositions
Journal Article · Thu Aug 15 00:00:00 EDT 2013 · Journal of Solid State Chemistry · OSTI ID:22274016

RKKY coupled local-moment magnetism in NaFe1xCuxAs
Journal Article · Fri Oct 22 00:00:00 EDT 2021 · Physical Review. B · OSTI ID:1979666