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Some recent efforts in chemical hydrogen storage at Loa Alamos

Conference ·
OSTI ID:1043461

Within the transportation sector, a necessity towards realizing the use of hydrogen (H{sub 2}) as an alternative fuel, is its storage for controlled delivery. The U.S. DOE's Centers of Excellence (CoE) in H{sub 2} storage have pursued different methodologies (metal hydrides, chemical hydrides, and sorbents), for the express purpose of supplanting gasoline's current > 300 mile driving range. Chemical H{sub 2} storage has been dominated by one material, ammonia borane (H3B-NH3, AB), due to its high gravimetric capacity of H{sub 2} (19.6 wt %) and low molecular weight (30.7 g mol{sup -1} ). As such, a number of publications have described H{sub 2} release from amine boranes, yielding various rates depending on the method applied. The viability of any storage system is also dependent on efficient recyclability. Within our CoE we have thus endeavored to find efficient base-metal catalyzed AB dehydrogenation pathways and regeneration schemes for the spent fuel from H{sub 2} depleted AB. We will present some recent results in these areas in this vein.

Research Organization:
Los Alamos National Laboratory (LANL)
Sponsoring Organization:
DOE
DOE Contract Number:
AC52-06NA25396
OSTI ID:
1043461
Report Number(s):
LA-UR-10-08158; LA-UR-10-8158
Country of Publication:
United States
Language:
English

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