Performance of solid oxide fuel cells operaated with coal syngas provided directly from a gasification process

Journal Article · Sun Jan 01 04:00:00 EST 2012 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2012.04.050· OSTI ID:1043429

Hackett, G; Gerdes, K; Song, X; Chen, Y; Shutthanandan, V; Englehard, M; Zhu, Z; Thevuthasan, S; Gemmen, R

Solid oxide fuel cells (SOFCs) are being developed for integrated gasification power plants that generate electricity from coal at 50% efficiency. The interaction of trace metals in coal syngas with Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but test data from direct coal syngas exposure are sparsely available. This effort evaluates the significance of performance losses associated with exposure to direct coal syngas. Specimen are operated in a unique mobile test skid that is deployed to the research gasifier at NCCC in Wilsonville, AL. The test skid interfaces with a gasifier slipstream to deliver hot syngas to a parallel array of twelve SOFCs. During the 500 h test period, all twelve cells are monitored for performance at four current densities. Degradation is attributed to syngas exposure and trace material attack on the anode structure that is accelerated at increasing current densities. Cells that are operated at 0 and 125 mA cm{sup 2} degrade at 9.1 and 10.7% per 1000 h, respectively, while cells operated at 250 and 375 mA cm{sup 2} degrade at 18.9 and 16.2% per 1000 h, respectively. Spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

• Research Organization: National Energy Technology Laboratory - In-house Research; National Energy Technology Laboratory (NETL), Pittsburgh, PA, and Morgantown, WV (United States)
• Sponsoring Organization: USDOE Office of Fossil Energy (FE)
• OSTI ID: 1043429
• Report Number(s): NETL-PUB-241
• Journal Information: Journal of Power Sources, Journal Name: Journal of Power Sources Vol. 214; ISSN JPSODZ; ISSN 0378-7753
• Publisher: Elsevier
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
30 DIRECT ENERGY CONVERSION
99 GENERAL AND MISCELLANEOUS
ANODES
CARBON
COAL
EFFICIENCY
ELECTRICITY
GASIFICATION
PERFORMANCE
PHOSPHORUS
POWER PLANTS
SOLID OXIDE FUEL CELLS
SULFUR
Solid oxide fuel cell
THERMODYNAMICS
coal syngas
gasification
multi-cell array
particle induced X-ray emission
transmission electron microscopy