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Dehydrated Prussian Blues for CO2 Storage and Separation Applications

Journal Article · · CrystEngComm
DOI:https://doi.org/10.1039/C0CE00199F· OSTI ID:1042562
Adsorption isotherms of pure gases present in flue and natural gas including CO2, N2, CH4 and water were studied using prussian blues of chemical formula M3[Co(CN)6]2 (M = Cu, Ni, Mn). These materials adsorbed 8-12 wt % of CO2 at room temperature and 1 bar of pressure with heats of adsorption ranging from 6 to 16 kcal/mol.
Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
1042562
Report Number(s):
PNNL-SA-73618; AA3010000
Journal Information:
CrystEngComm, Journal Name: CrystEngComm Journal Issue: 12 Vol. 12
Country of Publication:
United States
Language:
English

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