Kinetic Control of Metal–Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering
Journal Article
·
· Angewandte Chemie International Edition
The mechanism behind the multistep synthesis of two metal-organic frameworks sharing the same metal and organic precursors was revealed by in-situ time-resolved small- and wide-angle X-ray scattering. Key factors governing the crystal assembly could be established (see picture: C gray, H white, N blue, O red, Al yellow, Cl green), including solvent, temperature, and precursor concentration.
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Organization:
- USDOE SC OFFICE OF SCIENCE (SC)
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 1041598
- Report Number(s):
- BNL-96709-2011-JA; R&D Project: LS001; TRN: US201212%%16
- Journal Information:
- Angewandte Chemie International Edition, Vol. 50, Issue 41; ISSN 1433-7851
- Country of Publication:
- United States
- Language:
- English
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