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Electric field-induced deformation of polyelectrolyte gels

Conference ·
OSTI ID:103516

Water-swollen polyelectrolyte gels deform in an electric field. We observed that the sign and magnitude of the deformation is dependent on the nature of the salt bath in which the gel is immersed and electrocuted. These results are compatible with a deformation mechanism based upon creation of ion density gradients by the field which, in turn, creates osmotic pressure gradients within the gel. A consistent interpretation results only if gel mobility is allowed as well as free ion diffusion and migration.

Research Organization:
Sandia National Labs., Albuquerque, NM (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC04-94AL85000; AC04-76DP00789
OSTI ID:
103516
Report Number(s):
CONF-9203127--2; ON: DE95016546
Country of Publication:
United States
Language:
English

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